469777

6-Chloro-1-hexyne

98%

• Synonym(s): (4-Chlorobutyl)acetylene, 1-Chlorohex-5-yne
• Linear Formula: Cl(CH₂)₄C≡CH
• CAS Number: 10297-06-0
• Molecular Weight: 116.59
• MDL number: MFCD00013697
• UNSPSC Code: 12352100
• PubChem Substance ID: 24870482
• NACRES: NA.22

Properties

• Assay: 98%
• refractive index: n20/D 1.451 (lit.)
• bp: 83 °C/95 mmHg (lit.)
• density: 0.962 g/mL at 25 °C (lit.)
• SMILES string: ClCCCCC#C
• InChI: 1S/C6H9Cl/c1-2-3-4-5-6-7/h1H,3-6H2
• InChI key: ZUKOCGMVJUXIJA-UHFFFAOYSA-N

Description

General description

6-Chloro-1-hexyne is a halogenated hydrocarbon. It shows high reactivity in milling process during the synthesis of chloroalkyl-functionalized silicon nanoparticles due to the presence of triple bond.

Application

6-Chloro-1-hexyne was used in the preparation of novel bis(indolyl)maleimide pyridinophanes and disubstituted polyacetylenes bearing naphthalene pendants with varying spacer lengths. It may be used in the preparation of diethyl 6-chloro-1-hexynylphosphonate, by lithiation with n-BuLi followed by the reaction with diethyl chlorophosphate.

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Warning
• Hazard Statements: H226,H315,H319,H335
• Precautionary Statements: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 98.6 °F - closed cup
• Flash Point(C): 37 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves