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Sigma-Aldrich

Ferrocenium hexafluorophosphate

97%

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About This Item

Empirical Formula (Hill Notation):
C10H10F6FeP
CAS Number:
11077-24-0
Molecular Weight:
331.00
MDL number:
MFCD00192173
UNSPSC Code:
12352300
PubChem Substance ID:
24864219
NACRES:
NA.22

Assay

97%

form

powder

reaction suitability

core: iron
reagent type: catalyst

SMILES string

[Fe+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.F[P-](F)(F)(F)(F)F

InChI

1S/2C5H5.F6P.Fe/c2*1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-5H;;/q;;-1;+1

InChI key

JTRCXNUQIANBAN-UHFFFAOYSA-N

Application

The ferrocenium cation has been used to prepare catalysts for the asymmetric epoxidation of olefins, carbonylations of nitroaromatics, and the isomerization of a strained diene.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Giorgia Zampardi et al.
Physical chemistry chemical physics : PCCP, 19(41), 28381-28387 (2017-10-17)
High voltage operating active materials are among the most promising components for positive electrodes of future high energy lithium-ion batteries. However, the operating potential range of such materials often exceeds anodically the thermodynamic stability window of the electrolyte. A surface
Johanna Karppi et al.
Frontiers in chemistry, 8, 11-11 (2020-02-13)
Pyranose dehydrogenases (PDHs; EC 1.1.99.29; AA3_2) demonstrate ability to oxidize diverse carbohydrates. Previous studies of these enzymes have also uncovered substrate-dependent regioselectivity, along with potential to introduce more than one carbonyl into carbohydrate substrates. Enzymatic oxidation of carbohydrates facilitates their
Go Tajima et al.
Molecular genetics and metabolism, 119(4), 322-328 (2016-11-20)
Medium-chain acyl-CoA dehydrogenase (MCAD) deficiency is a representative disorder of fatty acid oxidation and is one of the most prevalent inborn errors of metabolism among Caucasian populations. In Japan, however, it was as late as 2000 when the first patient
Krishnan Venkatasubbaiah et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(2), 444-458 (2007-12-12)
A series of mixed-valent (MV) complexes [(FeCp)2(mu-C10H6(BPh)2)]+X ([1+]X; X=I 5, PF6, SbF6, B(C6F5)4) were prepared by oxidation of diboradiferrocene [(FeCp)2(mu-C10H6(BPh)2)] (1) with I 2, AgPF6, and AgSbF6, respectively, and through anion exchange of the I 5(-) salt with [Li(Et2O)x][B(C6F5)4] in
Tetrahedron Asymmetry, 2, 481-481 (1991)
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