360074
Magnesium bromide
98%
Synonym(s):
Ddibromomagnesium, Magnesium bromide salt, Magnesium dibromide
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About This Item
Linear Formula:
MgBr2
CAS Number:
Molecular Weight:
184.11
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
form
powder
mp
711 °C (lit.)
density
3.72 g/mL at 25 °C (lit.)
SMILES string
Br[Mg]Br
InChI
1S/2BrH.Mg/h2*1H;/q;;+2/p-2
InChI key
OTCKOJUMXQWKQG-UHFFFAOYSA-L
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Application
Magnesium bromide (MgBr2) can be used as a catalyst in:
- Acetylation and benzoylation of alcohols (primary and secondary) with acid anhydrides.
- In the synthesis of dihydropyrimidinones , trifluoromethylnaphthalenes , substituted 1,2,3,4 tetrahydropyrimidin-2-ones .
- In the preparation of Aldol derivatives by hydrogenation of Baylis-Hillman olefins.
- Deprotection of SEM (2-(Trimethylsilyl)ethoxymethyl) ether group.
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Magnesium bromide mediated highly diastereoselective heterogeneous hydrogenation of olefins
Bouzide, Abderrahim
Organic Letters, 4(8), 1347-1350 (2002)
Synthesis of trifluoromethylnaphthalenes
Mellor JM, et al.
Tetrahedron, 56(51), 10067-10074 (2000)
Magnesium bromide catalysed acylation of alcohols
Pansare SV, et al.
Synthetic Communications, 30(14), 2587-2592 (2000)
A facile and efficient one-pot synthesis of dihydropyrimidinones catalyzed by magnesium bromide under solvent-free conditions
Salehi H and Guo Q-X
Synthetic Communications, 34(1), 171-179 (2004)
Novel deprotection of SEM ethers: a very mild and selective method using magnesium bromide
Vakalopoulos A and Hoffmann HMR
Organic Letters, 2(10), 1447-1450 (2000)
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