291390

p-Tolyl acetate

99%

• Synonym(s): p-Cresyl acetate
• Linear Formula: CH₃CO₂C₆H₄CH₃
• CAS Number: 140-39-6
• Molecular Weight: 150.17
• EC Number: 205-413-1
• MDL number: MFCD00008703
• UNSPSC Code: 12352100
• PubChem Substance ID: 24857530
• NACRES: NA.22

Properties

• Assay: 99%
• refractive index: n20/D 1.501 (lit.)
• bp: 210-211 °C (lit.)
• density: 1.047 g/mL at 25 °C (lit.)
• SMILES string: CC(=O)Oc1ccc(C)cc1
• InChI: 1S/C9H10O2/c1-7-3-5-9(6-4-7)11-8(2)10/h3-6H,1-2H3
• InChI key: CDJJKTLOZJAGIZ-UHFFFAOYSA-N

Description

General description

The Fries rearrangement of p-tolyl acetate has been investigated using the H-form of various zeolites as catalysts. Mechanism of photo-Fries rearrangement of p-tolyl acetate has been studied.

Application

p-Tolyl acetate has been used in the total synthesis of (−)-incrustoporin.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302
• Precautionary Statements: P264 - P270 - P301 + P312 - P501
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 2
• Flash Point(F): 194.0 °F - closed cup
• Flash Point(C): 90 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves