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256447

Sigma-Aldrich

Bis(cyclopentadienyl)molybdenum(IV) dichloride

95%

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About This Item

Empirical Formula (Hill Notation):
C10H10Cl2Mo
CAS Number:
12184-22-4
Molecular Weight:
297.03
MDL number:
MFCD00009948
UNSPSC Code:
12352103
PubChem Substance ID:
24855528
NACRES:
NA.23

Assay

95%

form

crystalline powder
powder, crystals or chunks

reaction suitability

core: molybdenum
reagent type: catalyst

SMILES string

Cl[Mo]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Mo/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

YQZUTDPJTAZPQJ-UHFFFAOYSA-L

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Jenny B Waern et al.
Inorganic chemistry, 43(1), 206-213 (2004-01-06)
The relative affinity of molybdocene dichloride (Cp(2)MoCl(2)) for the thiol, amino, carboxylate, phosphate(O) and heterocyclic(N) donor ligands present in amino acids and nucleotides, has been studied in aqueous solutions at pH 2-7, using (1)H, (13)C and (31)P NMR spectroscopy. Molybdocene
E Tonew et al.
Zentralblatt fur Bakteriologie, Mikrobiologie und Hygiene. 1. Abt. Originale A, Medizinische Mikrobiologie, Infektionskrankheiten und Parasitologie = International journal of microbiology and hygiene. A, Medical microbiology, infectious..., 250(4), 425-430 (1981-11-01)
In view of the fact that bis cyclopentadienyl metal dihalides are known to be anti-tumour drugs, we have investigated the antiviral activity of this type of coordination compounds. Bis cyclopentadienyl titanium dichloride (a) has shown significant antiviral efficiency in vitro
Louis Y Kuo et al.
Inorganic chemistry, 44(15), 5537-5541 (2005-07-19)
Thiophosphinate hydrolysis involving P-S bond scission is desirable for the degradation of organophosphate neurotoxins, and we report the first case for such a hydrolytic process by an organometallic compound. The metallocene, bis(cyclopentadienyl)molybdenum(IV) dichloride, Cp(2)MoCl(2) (Cp = eta(5)-C(5)H(5)), hydrolyzes a variety
Jenny B Waern et al.
Journal of medicinal chemistry, 48(6), 2093-2099 (2005-03-18)
The effect of aqueous solubility, charge, and lability of four thiol derivatives of the antitumor metallocene molybdocene dichloride (Cp(2)MoCl(2)) on the cell uptake and cytotoxicity against V79 Chinese hamster lung cells has been determined. Addition of 4-thiol-2,3,5,6-tetrafluorobenzoic acid, 1-thio-beta-d-glucose, and
P Manohari Abeysinghe et al.
Dalton transactions (Cambridge, England : 2003), (32)(32), 3474-3482 (2007-08-08)
This Perspective will focus on recent developments in the field of antitumour metallocenes structurally related to titanocene dichloride. Despite extensive testing of titanocene dichloride which culminated in phase I and II clinical trials, further trials have been abandoned. While DNA
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