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241288

Sigma-Aldrich

Triphenyl phosphate

≥99%

Synonym(s):

Triphenoxyphosphine oxide

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About This Item

Linear Formula:
(C6H5O)3PO
CAS Number:
115-86-6
Molecular Weight:
326.28
Beilstein:
1888236
EC Number:
204-112-2
MDL number:
MFCD00003031
UNSPSC Code:
12352100
PubChem Substance ID:
24854472
NACRES:
NA.22

vapor pressure

1.3 mmHg ( 200 °C)

Assay

≥99%

bp

244 °C/10 mmHg (lit.)

mp

48-50 °C (lit.)

solubility

acetone: soluble(lit.)
alcohol: moderately soluble(lit.)
benzene: soluble(lit.)
chloroform: soluble(lit.)
diethyl ether: soluble(lit.)
water: insoluble(lit.)

SMILES string

O=P(Oc1ccccc1)(Oc2ccccc2)Oc3ccccc3

InChI

1S/C18H15O4P/c19-23(20-16-10-4-1-5-11-16,21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H

InChI key

XZZNDPSIHUTMOC-UHFFFAOYSA-N

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General description

Triphenyl phosphate, an organophosphorus flame retardant (PFR), was determined in human milk sample.

Application

Triphenyl phosphate was used as an internal standard in the screening and quantification of pesticide residues in vegetables and fruits.

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

428.0 °F - closed cup

Flash Point(C)

220 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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O B Jonsson et al.
Journal of chromatography. B, Biomedical sciences and applications, 755(1-2), 157-164 (2001-06-08)
An extractor has been developed for microporous membrane liquid-liquid extraction (MMLLE) of lipophilic xenobiotics at trace levels in biological fluids. This new construction allows the sample phase to be stirred, while the organic phase is pumped. The extractor was evaluated
Nele Van den Eede et al.
Talanta, 89, 292-300 (2012-01-31)
A new method was optimized for the simultaneous determination of several flame retardants (FRs) in indoor dust, namely polybrominated diphenyl ethers (PBDEs), hexabromocyclododecanes (HBCDs), novel brominated flame retardants (NBFRs) and organophosphate ester flame retardants (OPFRs). The method was based on
Gang Wu et al.
Pest management science, 63(5), 500-510 (2007-04-11)
The toxicities of three enzyme inhibitors and their synergistic effects on four insecticides were studied by using the dry film method on field populations of 18 species of insects collected in Jianxin and Shanjie, China, from 2003 to 2005. Meanwhile
Joon-Woo Kim et al.
Chemosphere, 116, 91-97 (2014-03-19)
In this study, the concentrations of 10 organophosphorus flame retardants (PFRs) were determined in 89 human breast milk samples collected from Japan, the Philippines and Vietnam. Among the targeted PFRs, tris(2-chloroexyl) phosphate (TCEP) and triphenyl phosphate (TPHP) were the predominant
M I Picollo et al.
Journal of medical entomology, 37(5), 721-725 (2000-09-27)
Permethrin-resistant colonies of Pediculus capitis (De Geer) from Buenos Aires were used to establish a resistance profile and to examine resistance mechanisms. All permethrin-resistant head lice (resistance ratio from 52.8 to > 88.7) were also resistant to d-phenothrin (resistance ratio
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