Skip to Content
Merck
All Photos(1)

Documents

183695

Sigma-Aldrich

2′-Bromoacetophenone

99%

Synonym(s):

1-Acetyl-2-bromobenzene

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
BrC6H4COCH3
CAS Number:
2142-69-0
Molecular Weight:
199.04
Beilstein:
1931534
EC Number:
218-398-1
MDL number:
MFCD00000067
UNSPSC Code:
12352100
PubChem Substance ID:
24851070
NACRES:
NA.22

Quality Level

100

Assay

99%

form

liquid

refractive index

n20/D 1.568 (lit.)

density

1.476 g/mL at 25 °C (lit.)

SMILES string

CC(=O)c1ccccc1Br

InChI

1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3

InChI key

PIMNFNXBTGPCIL-UHFFFAOYSA-N

Related Categories

General description

2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.

Application

2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 1

1 of 1

2-Bromo-4′-methylacetophenone 90%

Sigma-Aldrich

159530

2-Bromo-4′-methylacetophenone

Palladium-catalysed convenient synthesis of 3-methyleneisoindolin-1-ones.
Cho CS, et al.
Synthetic Communications, 32(!2), 1821-1827 (2002)
Non-Condensed Trifluoromethylated 5, 5-Bicycles: Synthesis of 2-[3-Alkyl (phenyl)-1H-pyrazol-1-yl]-4-phenyl-5-alkylthiazole and-4, 5, 6, 7-tetrahydrobenzothiazole Systems.
Bonacorso HG, et al.
Synthesis, 2002(08), 1079-1083 (3003)
Enantioselective alkynylation of aromatic ketones catalyzed by chiral camphorsulfonamide ligands.
Gui Lu et al.
Angewandte Chemie (International ed. in English), 42(41), 5057-5058 (2003-11-05)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service