157295
Diethyl trans-1,2-cyclopropanedicarboxylate
97%
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About This Item
Linear Formula:
C3H4(CO2C2H5)2
CAS Number:
Molecular Weight:
186.21
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
liquid
refractive index
n20/D 1.441 (lit.)
bp
70-75 °C/1 mmHg (lit.)
density
1.061 g/mL at 25 °C (lit.)
functional group
ester
SMILES string
CCOC(=O)[C@@H]1C[C@H]1C(=O)OCC
InChI
1S/C9H14O4/c1-3-12-8(10)6-5-7(6)9(11)13-4-2/h6-7H,3-5H2,1-2H3/t6-,7-/m1/s1
InChI key
SXLDHZFJMXLFJU-RNFRBKRXSA-N
General description
Diethyl trans-1,2-cyclopropanedicarboxylate was obtained from the reaction of bis(acetonitrile)bis(diethyl fumarate)cobalt(0) with dibromomethane.[1]
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
208.4 °F - closed cup
Flash Point(C)
98.00 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Cyclopropanation of dimethyl fumarate and maleate with gem-dihalides catalyzed by Co (0)-or Ni (0)-complex and zinc.
Kanai H, et al.
Bulletin of the Chemical Society of Japan, 56(6), 1592-1597 (1983)
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