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Sigma-Aldrich

Titanium(IV) fluoride

Synonym(s):

Titanium tetrafluoride, Titanium fluoride

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About This Item

Linear Formula:
TiF4
CAS Number:
7783-63-3
Molecular Weight:
123.86
EC Number:
232-017-6
MDL number:
MFCD00042545
UNSPSC Code:
12161600
PubChem Substance ID:
24860116
NACRES:
NA.22

form

powder and chunks

Quality Level

200

reaction suitability

core: titanium
reagent type: catalyst

density

2.798 g/mL at 25 °C (lit.)

SMILES string

F[Ti](F)(F)F

InChI

1S/4FH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XROWMBWRMNHXMF-UHFFFAOYSA-J

Application

Catalyst for:
  • Chemoselective synthesis and deprotection of geminal diacetates of aldehydes
Used for preparation of glycosyl fluorides; glycosylation; preparation of fluorohydrins; addition of carbanions to aldehydes and imines.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302 + H312 + H332,H314

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Annette Wiegand et al.
Oral health & preventive dentistry, 8(2), 159-164 (2010-07-01)
The present review summarises the effects of titanium tetrafluoride (TiF(4)) on the development and progression of carious and erosive lesions. The mode of action of TiF(4) is due to the formation of an acid-stable surface layer, which provides mechanical protection
Shimizu, M.; Morita, A.; Kaga, T.
Tetrahedron Letters, 40, 8401-8401 (1999)
M Dündar et al.
Journal of dental research, 90(1), 93-98 (2010-10-14)
Hybrid-layer degradation occurs because of acidic properties of currently used adhesive systems. Titanium tetrafluoride couples with tooth surface, and titanium compounds are not substituted. Caffeic acid phenethyl esther inhibits endogenous matrix metalloproteinases that cause hybrid-layer degradation. It was hypothesized that
A Wiegand et al.
Caries research, 43(4), 269-277 (2009-05-15)
This study aimed to analyse and compare the protective effect of buffered (pH 3.5) and native (pH 1.2) TiF(4) in comparison with NaF solutions on enamel erosion. Bovine samples were pretreated with 1.50% TiF(4) or 2.02% NaF (both 0.48 M
A M Vieira et al.
Caries research, 45(2), 142-147 (2011-04-02)
The aims of this study were to compare daily versus single applications of low-concentration TiF(4) solutions for reduction of enamel erosion and to evaluate the enamel surface loss due to application of these solutions. Sixty bovine enamel samples were randomly
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