463558
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane
Synonym(s):
Verkade superbase
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About This Item
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mp
110-115 °C (lit.)
SMILES string
CN1CCN2CCN(C)P1N(C)CC2
InChI
1S/C9H21N4P/c1-10-4-7-13-8-5-11(2)14(10)12(3)6-9-13/h4-9H2,1-3H3
InChI key
PCYSWBQHCWWSFW-UHFFFAOYSA-N
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Application
2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane is involved as a reactant in:
- Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies.
- Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica.
- Protection / deprotection strategies for diazeniumdiolate chemistry.
- Encaging of the molecule to study the change in its catalytic ability.
- C-N coupling reactions.
- Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction.
Reactant involved in:
- Studies of N-heterocyclic carbene ligand effects on metal hydride bond energies
- Synthesis of heterogenous basic catalysts immobilized on SBA-15 silica
- Protection / deprotection strategies for diazeniumdiolate chemistry
- Encaging of the molecule to study change in its catalytic ability
- C-N coupling reactions
- Derivative synthesis used as a promoter for aza and thia-Michael reaction and Strecker reaction
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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