738883
1-Methyl-2-azaadamantane-N-oxyl
97%
Synonym(s):
1-Me-AZADO
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About This Item
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Quality Level
Assay
97%
form
solid
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
mp
87-93 °C
greener alternative category
storage temp.
2-8°C
SMILES string
CC12CC3CC(CC(C3)N1[O])C2
InChI
1S/C10H16NO/c1-10-5-7-2-8(6-10)4-9(3-7)11(10)12/h7-9H,2-6H2,1H3
InChI key
IBNXYCCLPCGKDM-UHFFFAOYSA-N
General description
1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO), a sterically less hindered nitroxyl radical, is widely used as catalyst. It is chemically stable and exhibits superior catalytic performance.
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Application
1-Methyl-2-azaadamantane-N-oxyl (1-Me-AZADO) may be employed as catalyst for the aerobic oxidation of alcohols and sterically hindered alcohols.
Catalytic oxidant for greener oxidation of alcohols under aerobic, solvent-free conditions. Recoverable and recyclable.
Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation
Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Efficient oxidation of alcohols electrochemically mediated by azabicyclo-N-oxyls.
Tetrahedron Letters, 49(1), 48-52 (2008)
Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation.
Green Chemistry, 13(7), 1659-1663 (2011)
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