561673

1-Naphthylmagnesium bromide solution

0.25 M slurry in THF

• Empirical Formula (Hill Notation): C₁₀H₇BrMg
• CAS Number: 703-55-9
• Molecular Weight: 231.37
• MDL number: MFCD00015768
• UNSPSC Code: 12352103
• PubChem Substance ID: 24879961
• NACRES: NA.22

Properties

• reaction suitability: reaction type: Grignard Reaction
• Quality Level: 100
• concentration: 0.25 M slurry in THF
• bp: 65 °C
• density: 0.908 g/mL at 25 °C
• SMILES string: Br[Mg]c1cccc2ccccc12
• InChI: 1S/C10H7.BrH.Mg/c1-2-6-10-8-4-3-7-9(10)5-1;;/h1-7H;1H;/q;;+1/p-1
• InChI key: PZIIGUMPOSVMSD-UHFFFAOYSA-M

Description

Application

1-Naphthylmagnesium bromide can be used:

• To prepare unsymmetrical chiral diene ligands, which are applicable in asymmetric transformation reactions.
• As a starting material in the synthesis of methyl (2Z,4E)-2-methylsulfanyl-5-(1-naphthyl)-4-nitro-2,4-pentadienoate, a naphthylnitrobutadiene based anti-proliferative compound.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• Pictograms: GHS02,GHS08,GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H302,H314,H335,H351
• Precautionary Statements: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014,EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 1.4 °F - closed cup
• Flash Point(C): -17 °C - closed cup