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33356

Supelco

BF3 - Methanol

10 % (w/w), pkg of 20 × 1 mL

Synonym(s):

Boron trifluoride

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About This Item

UNSPSC Code:
41116105

grade

for GC derivatization

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

reagent type: derivatization reagent
reaction type: Esterifications

packaging

pkg of 20 × 1 mL

concentration

10 % (w/w)

storage temp.

2-8°C

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General description

Boron trifluoride is a colourless gas which readily reacts with water to form hydrates. It has been widely used as a catalyst for polymerizations, alkylations and condensation reactions. It also finds application in being used as gas flux for internal soldering or brazing. It also has its uses in extinguisher for magnesium fires.

Application

It was used in transmethylation of 1,2-Diacylglycerol (DAG) containing fractions which were purified using HPLC. It may be used to treat lipids during determination of fatty acid methyl esters and dimethylacetals using GC.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1

Target Organs

Eyes, Kidney

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

60.8 °F - closed cup

Flash Point(C)

16 °C - closed cup


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S B Bocckino et al.
The Journal of biological chemistry, 260(26), 14201-14207 (1985-11-15)
1,2-Diacylglycerol (DAG) was measured in neutral lipid extracts from isolated hepatocytes using high pressure liquid chromatography followed by refractive index detection. Maximally effective doses of epinephrine, angiotensin II, and vasopressin increased DAG by approximately 65, 80, and 180-250%, respectively, with
Separation and quantitative determination of lactic, pyruvic, fumaric, succinic, malic, and citric acids by gas chromatography.
E Hautala et al.
Analytical biochemistry, 30(1), 32-39 (1969-07-01)
J.Horner et al.
Analytical Chemistry, 46, 110-110 (1974)
PREPARATION OF FATTY ACID METHYL ESTERS AND DIMETHYLACETALS FROM LIPIDS WITH BORON FLUORIDE--METHANOL.
W R MORRISON et al.
Journal of lipid research, 5, 600-608 (1964-10-01)
B.Hallgren and S. Larsson
Journal of Lipid Research, 3, 32-32 (1962)

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