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Sigma-Aldrich

Iridium(III) acetylacetonate

97%

Synonym(s):

Ir(acac)3

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About This Item

Linear Formula:
[CH3COCH=C(O-)CH3]3Ir
CAS Number:
15635-87-7
Molecular Weight:
489.54
EC Number:
239-711-8
MDL number:
MFCD00015353
UNSPSC Code:
12352103
PubChem Substance ID:
24860124
NACRES:
NA.23

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: iridium
reagent type: catalyst

mp

269-271 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Ir](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Ir/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

HLYTZTFNIRBLNA-LNTINUHCSA-K

General description

Iridium(III) acetylacetonate is a thermallystable organic precursor widely used in the chemical vapor deposition process.It has relatively high saturated vapor pressure and low sublimationenthalpy.

Application

Iridium(III)acetylacetonate can be used as a precursor in the preparation of:
  • Iridium coatings by metallo-organic chemical vapor deposition (MOCVD).
  • Iridium oxide nanoclusters (IrOx). ZrOCoII−IrOx can be used as a catalyst in carbon dioxide reduction.
  • MgF2–MgO supported Iridium catalyst for CO oxidation.(3)

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Tao Yang et al.
Nanoscale, 11(48), 23206-23216 (2019-11-30)
Fuel cells are expected to be one of the most promising alternatives to the increasingly scarce fossil fuels, and Pt is the most commonly used catalyst for anodic and cathodic electrochemical reactions. To realize large-scale commercialization, it is most urgent
Wooyul Kim et al.
Journal of the American Chemical Society, 136(31), 11034-11042 (2014-07-18)
An all-inorganic polynuclear unit consisting of an oxo-bridged binuclear ZrOCo(II) group coupled to an iridium oxide nanocluster (IrO(x)) was assembled on an SBA-15 silica mesopore surface. A photodeposition method was developed that affords coupling of the IrO(x) water oxidation catalyst
Tao Zhang et al.
Nanoscale, 9(3), 1154-1165 (2016-12-24)
For the first time, shape-tunable Pt-Ir alloy nanocatalysts including both single-crystalline (nano-octahedra (NOs), nano-truncated octahedra (NTOs), nanocubes (NCs)) and polycrystalline (nanocluster flowers (NCFs), nanowires (NWs), nano-short-chains (NSCs), and nano-octahedral stars (NOSs)) ones were synthesized with a facile one-pot solvothermal method
Jongsik Park et al.
ACS nano, 11(6), 5500-5509 (2017-06-10)
Nanoframe electrocatalysts have attracted great interest due to their inherently high active surface area per a given mass. Although recent progress has enabled the preparation of single nanoframe structures with a variety of morphologies, more complex nanoframe structures such as

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