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87580

Sigma-Aldrich

Tetrakis(decyl)ammonium bromide

≥99.0% (AT)

Synonym(s):

TDAB, Tetra-decylammonium bromide

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About This Item

Linear Formula:
[CH3(CH2)9]4N(Br)
CAS Number:
Molecular Weight:
659.01
Beilstein:
5842649
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥99.0% (AT)

form

powder

SMILES string

[Br-].CCCCCCCCCC[N+](CCCCCCCCCC)(CCCCCCCCCC)CCCCCCCCCC

InChI

1S/C40H84N.BrH/c1-5-9-13-17-21-25-29-33-37-41(38-34-30-26-22-18-14-10-6-2,39-35-31-27-23-19-15-11-7-3)40-36-32-28-24-20-16-12-8-4;/h5-40H2,1-4H3;1H/q+1;/p-1

InChI key

AHNISXOXSNAHBZ-UHFFFAOYSA-M

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General description

Tetrakis(decyl)ammonium bromide is a cationic surfactant.

Tetrakis(decyl)ammonium bromide is a quaternary ammonium/phosphonium salt used as an ion-pair agent, and for the modification of bentonite.

Application

Tetrakis(decyl)ammonium bromide acts as a phase transfer agent for:
  • Platinum salts from aqueous to organic phase during the synthesis of platinum nanocrystals.
  • Gold ions from an aqueous to an organic phase during the synthesis of gold nanoparticles.
  • The alkylation of (E)‐pyridine aldoximes and (E)‐ketoximes with dihalohydrins.
It has been used as a reactant in the synthesis of ionic monomers to produce soft thermoplastic polyurethanes(TPU).

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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O-Alkylation of pyridine aldo-and ketoximes with dihalohydrins under phase-transfer conditions
Kocak A, et al.
Synthetic Communications, 37, 1155-1165 (2007)
Electron tomography and 3D molecular simulations of platinum nanocrystals.
Florea I
Nanoscale, 4(16), 5125-5131 (2012)
Ionomers for tunable softening of thermoplastic polyurethane
Zander Z, et al.
Macromolecules, 49, 926-934 (2016)
Derivatization of saturated long-chain fatty acids with phenacyl bromide in non-ionic micelles
Ilana and Zamir
Journal of Chromatography A, 586, 347-350 (1991)
Use of purified and modified bentonites in linear low-density polyethylene/organoclay/compatibilizer nanocomposites
Tijen S et al.
Journal of Applied Polymer Science, 124, 2430-2440 (2012)

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