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Sigma-Aldrich

Cerium(IV) oxide-samarium doped

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<0.5 μm particle size, powder, contains 20 mol % samarium as dopant

Synonym(s):

SDC-20, SDC, Samarium-doped ceria

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About This Item

Empirical Formula (Hill Notation):
CeO2
Molecular Weight:
172.11
MDL number:
MFCD04974842
UNSPSC Code:
26111700
PubChem Substance ID:
329764915
NACRES:
NA.23

form

powder

contains

20 mol % samarium as dopant

composition

Sm0.2Ce0.8O1.9

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surface area

10-14 m2/g

particle size

0.1-0.5 μm (d50)
<0.5 μm

bulk density

1.787 g/mL

greener alternative category

, Enabling

SMILES string

[Sm].O=[Ce]=O

InChI

1S/Ce.2O.Sm

InChI key

AQGZISMLQKBRRO-UHFFFAOYSA-N

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General description

Cerium(IV) oxide-samarium doped powder (20% mol samarium doped) (SDC-20) is an electrolytic material with a high oxygen ion conductivity. Samarium ion acts as an aliovalent cation that can be incorporated into the host lattice to increase the oxygen vacancy concentration and improve the oxide ion conduction in cerium oxide. It can be synthesized by reverse strike co-precipitation technique.
Samarium doped ceria may be used as an electrolyte in solid oxide fuel cells (SOFCs). Electrical conductivity as a function of temperature of doped ceria was investigated in a study. Relation of dopant type, oxygen vacancy ordering and ionic conductivity was investigated by transmission electron microscopy and electron energy loss spectroscopy.
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Application

Cerium(IV) oxide-samarium doped can be used in the fabrication of solid oxide fuel cells (SOFCs), which can further be used as environmentally-friendly sources of alternative energy.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Jun Zhang et al.
Scientific reports, 4, 7082-7082 (2014-11-19)
In this work, redox-active Mn or Cr is introduced to the B site of redox stable perovskite Sr(0.95)Ti(0.9)Nb(0.1)O3.00 to create oxygen vacancies in situ after reduction for high-temperature CO2 electrolysis. Combined analysis using X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron
Hugo J Avila-Paredes et al.
Physical chemistry chemical physics : PCCP, 11(38), 8580-8585 (2009-09-24)
We report a correlation between oxygen ionic conductivity and the enthalpy of formation of trivalent-doped ceria from the component binary oxides observed at relatively low temperatures (150-275 degrees C). The bulk conductivities of La-doped ceria samples identical to those previously
Diego H Sanchez et al.
PLoS genetics, 10(11), e1004806-e1004806 (2014-11-21)
Epigenetic mechanisms suppress the transcription of transposons and DNA repeats; however, this suppression can be transiently released under prolonged heat stress. Here we show that the Arabidopsis thaliana imprinted gene SDC, which is silent during vegetative growth due to DNA
Stephan Immenschuh et al.
Transplantation, 99(1), 56-62 (2014-08-15)
Treatment of patients with antibody-mediated rejection (AMR) after kidney transplantation by rituximab and plasmapheresis is ambiguous. Because of its unknown efficiency and serious side effects, biomarkers, which are predictive for responsiveness to this treatment in AMR patients, are required. Twenty
Fabrication and electrochemical properties of epitaxial samarium-doped ceria films on SrTiO3-buffered MgO substrates
Sanna S, et al.
Advances in Functional Materials, 19(11), 1713-1719 (2009)
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