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96483

Sigma-Aldrich

Zinc iodide

purum p.a., ≥98.0% (AT)

Synonym(s):

Diiodozinc, Zinc diiodide

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About This Item

Linear Formula:
ZnI2
CAS Number:
Molecular Weight:
319.20
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

purum p.a.

Quality Level

Assay

≥98.0% (AT)

form

powder or crystals

mp

445 °C (lit.)

density

4.74 g/mL at 25 °C (lit.)

anion traces

sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤500 mg/kg
Cd: ≤200 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤100 mg/kg
K: ≤500 mg/kg
Na: ≤500 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg

SMILES string

I[Zn]I

InChI

1S/2HI.Zn/h2*1H;/q;;+2/p-2

InChI key

UAYWVJHJZHQCIE-UHFFFAOYSA-L

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General description

Zinc iodide is a white crystalline Lewis acid often used as a starting material for synthesizing other zinc compounds, as a Lewis acid catalyst in organic reactions, and as an electrolyte additive.

Application

Zinc iodide can be used:
  • As a catalyst for one-pot synthesis of aminoindolizines via sequential A3 coupling/cycloisomerization.
  • As a catalyst for one-pot synthesis of quinoxalines.
  • As a precursor to synthesize highly luminescent quantum dots.
  • As a redox electrolyte in hybrid energy storage systems.
  • As a dopant to prepare highly flexible PVA composite films. The addition of zinc iodide enhances the optoelectronic properties of polymer composite.

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 2 Oral

Target Organs

Thyroid

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Nanoconfinement of redox reactions enables rapid zinc iodide energy storage with high efficiency
Juhan Lee, et al.
Journal of Materials Chemistry, 5, 12520-12527 (2017)
Large-Scale Synthesis of Highly Luminescent InP@ZnS Quantum Dots Using Elemental Phosphorus Precursor
Eunbyul Bang, et al.
Chemistry of Materials, 29, 4236-4243 (2017)
Zinc iodide: a mild and efficient catalyst for one-pot synthesis of aminoindolizines via sequential A 3 coupling/cycloisomerization
Subhajit Mishra, et al.
Royal Society of Chemistry Advances, 4, 6672-6676 (2014)
The effect of zinc iodide on the physicochemical properties of highly flexible transparent poly (vinyl alcohol) based polymeric composite films: opto-electrical performance
Bouzidi A , et al.
Journal of Materials Science: Materials in Electronics, 30, 11799-11806 (2019)
Efficient one-pot synthesis of quinoxalines in the presence of zinc iodide as catalyst
J N Sangshetti, et al.
Russian Journal of Organic chemistry, 45, 1116-1118 (2009)

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