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31510

Supelco

Bupirimate

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C13H24N4O3S
CAS Number:
41483-43-6
Molecular Weight:
316.42
Beilstein:
758056
EC Number:
255-391-2
MDL number:
MFCD00055518
UNSPSC Code:
41116107
PubChem Substance ID:
329753790
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCCCc1c(C)nc(NCC)nc1OS(=O)(=O)N(C)C

InChI

1S/C13H24N4O3S/c1-6-8-9-11-10(3)15-13(14-7-2)16-12(11)20-21(18,19)17(4)5/h6-9H2,1-5H3,(H,14,15,16)

InChI key

DSKJPMWIHSOYEA-UHFFFAOYSA-N

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General description

Bupirimate is an active ingredient in plant protection products and is commonly used as a systemic fungicide. It belongs to the family of pyrimidines and finds applications in controlling powdery mildew in roses and apple plantations.

Application

Bupirimate may be used as a reference standard in the determination of bupirimate in fruits using gas chromatography coupled with a flame photometric detector (GC-FPD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Warning

Hazard Statements

H312,H317,H351,H410

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1B

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL5991
BCCH2812
BCCH0089
BCCF5918
BCCD6163

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M J Jongen et al.
Journal of analytical toxicology, 16(1), 60-62 (1992-01-01)
An HPLC method was developed for estimation of dermal exposure of greenhouse workers to the pesticide bupirimate. Chromatography was performed on a cyano-modified silica column with methanol-water (6:4 by volume) containing 5 g/L ammonium sulfate as eluent. UV detection at
Identification of pesticide transformation products in agricultural soils using liquid chromatography/quadrupole-time-of-flight mass spectrometry.
Padilla-Sanchez.AJ, et al.
Rapid Communications in Mass Spectrometry, 26(09), 1091-1099 (2012)
Detoxification of bupirimate pesticide in aqueous solutions by electrochemical oxidation
Errami.M, et al.
Der Pharm Chem, 4, 297-310 (2012)
chromatography/quadrupole-time-of-flight mass spectrometry},
Ernst.FG, et al.
Journal of Chromatography A, 179(2), 351-354 (1979)
Yun-Hui Teng et al.
Chang Gung medical journal, 27(12), 877-886 (2005-03-10)
The purpose of this retrospective study was to determine whether epidural fentanyl-bupivacaine patient-controlled analgesia (PCA) was more efficacious and had fewer adverse effects than epidural or intravenous morphine PCA. We retrospectively retrieved data from 859 patients (mean age 64+/-7 years)
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