CRM01303
Cyantraniliprole
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonyme(s) :
3-Bromo-1-(3-chloro-2-pyridyl)-4′-cyano-2′-methyl-6′-(methylcarbamoyl)pyrazole-5-carboxanilide
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About This Item
Formule empirique (notation de Hill):
C19H14BrClN6O2
Numéro CAS:
Poids moléculaire :
473.71
Numéro MDL:
Code UNSPSC :
41116107
Nomenclature NACRES :
NA.24
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Qualité
certified reference material
TraceCERT®
Niveau de qualité
Gamme de produits
TraceCERT®
Durée de conservation
limited shelf life, expiry date on the label
Fabricant/nom de marque
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Température de stockage
2-8°C
Chaîne SMILES
O=C(C1=CC(Br)=NN1C2=C(Cl)C=CC=N2)NC3=C(C(NC)=O)C=C(C#N)C=C3C
InChI
1S/C19H14BrClN6O2/c1-10-6-11(9-22)7-12(18(28)23-2)16(10)25-19(29)14-8-15(20)26-27(14)17-13(21)4-3-5-24-17/h3-8H,1-2H3,(H,23,28)(H,25,29)
Clé InChI
DVBUIBGJRQBEDP-UHFFFAOYSA-N
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Description générale
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. The CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Cyantraniliprole, a second-generation diamide insecticide, activates the ryanodine receptors of insects to cause the release of Ca2+ ions resulting in muscle paralysis and death of the insect. It shows ovicidal, larvicidal, and adulticide activity, depending upon the pest species. It is used for cereal crops and vegetables, such as rice, peanuts, corn, tomatoes, green onions, and cucumbers for protection against lepidopteran and coleopteran pests.
Cyantraniliprole is approved for use in the European Union. The maximum residue limits (MRL) for cyantraniliprole in food crops, as per EU regulations are in the range of 0.01-15 mg/kg. As per a request received for cyantraniliprole MRL modification by an evaluating member state (EMS) on 28th January 2015, the EFSA has proposed an MRL of 0.5 mg/kg in strawberries, 0.2 mg/kg in the crop groups “herbal infusions from roots” and “root and rhizome spices”, 0.04 mg/kg on beans without pods, 0.15 mg/kg on peas without pods, and 0.1 mg/kg in globe artichokes. No MRL modifications were made for cherries, carrots, root and tuber vegetables, and brussels sprouts. Cyanantraniliprole is monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Cyantraniliprole, a second-generation diamide insecticide, activates the ryanodine receptors of insects to cause the release of Ca2+ ions resulting in muscle paralysis and death of the insect. It shows ovicidal, larvicidal, and adulticide activity, depending upon the pest species. It is used for cereal crops and vegetables, such as rice, peanuts, corn, tomatoes, green onions, and cucumbers for protection against lepidopteran and coleopteran pests.
Cyantraniliprole is approved for use in the European Union. The maximum residue limits (MRL) for cyantraniliprole in food crops, as per EU regulations are in the range of 0.01-15 mg/kg. As per a request received for cyantraniliprole MRL modification by an evaluating member state (EMS) on 28th January 2015, the EFSA has proposed an MRL of 0.5 mg/kg in strawberries, 0.2 mg/kg in the crop groups “herbal infusions from roots” and “root and rhizome spices”, 0.04 mg/kg on beans without pods, 0.15 mg/kg on peas without pods, and 0.1 mg/kg in globe artichokes. No MRL modifications were made for cherries, carrots, root and tuber vegetables, and brussels sprouts. Cyanantraniliprole is monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques.
Cyantraniliprole certified reference material (CRM) may also find following use:
Cyantraniliprole certified reference material (CRM) may also find following use:
- Study of DNA damage, oxidative stress, and biological toxicity caused in earthworm by cyantraniliprole
- Development of an isotope-labelled internal standard based method using ultra-high-performance liquid chromatography-tandem mass spectrometry for the analysis of chlorantraniliprole and cyantraniliprole in fruits, vegetables, and cereals
- Simultaneous determination of 8 new generation amide insecticides by ultrahigh performance liquid chromatography-tandem mass spectrometry in complex food matrices
- Estimation of five diamide insecticides using carbon nanotube multiplug filter for sample clean-up and ultrahigh-performance liquid chromatography-tandem mass spectrometry in food matrices
- Simultaneous analysis of five diamide insecticides in edible mushrooms by high-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS) and a modified QuEChERS procedure for extraction
Produits recommandés
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Informations légales
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Mention d'avertissement
Warning
Mentions de danger
Conseils de prudence
Classification des risques
Aquatic Acute 1 - Aquatic Chronic 1
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
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Modification of the existing maximum residue levels for cyantraniliprole in various crops
European Food Safety Authority (EFSA)
EFSA Journal, 4263 null
Zhou Lu et al.
Journal of agricultural and food chemistry, 67(39), 10977-10983 (2019-09-07)
In this study, an analytical method was developed and validated for simultaneous determination of five diamide insecticides (chlorantraniliprole, cyantraniliprole, flubendiamide, cyclaniliprole, and tetrachlorantraniliprole) in food matrices. Determination of the latter two diamide compounds is first reported. Samples were cleaned up
Xinglu Pan et al.
Analytical and bioanalytical chemistry, 407(14), 4111-4120 (2015-03-31)
A reliable and sensitive isotope-labelled internal standard method for simultaneous determination of chlorantraniliprole and cyantraniliprole in fruits (apple and grape), vegetables (cucumber and tomato) and cereals (rice and wheat) using ultra-high-performance liquid chromatography-tandem mass spectrometry was developed. Isotope-labelled internal standards
Fajun Tian et al.
Food chemistry, 333, 127468-127468 (2020-07-14)
In this study, a new method for simultaneous determination of cyantraniliprole, chlorantraniliprole, tetrachlorantraniliprole, cyclaniliprole and flubendiamide in edible mushrooms by high-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS) combined with a modified QuEChERS procedure. The samples were extracted using
Zhihua Qiao et al.
Chemosphere, 236, 124328-124328 (2019-07-17)
Cyantraniliprole is a second-generation diamide insecticide that exhibited excellent biological efficacy against a variety of pests. To assess the toxic impact of cyantraniliprole on earthworms, the levels of reactive oxygen species (ROS) and malondialdehyde (MDA), activities of superoxide dismutase (SOD)
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