71640

Phosphate de sodium dibasic

puriss. p.a., ACS reagent, anhydrous, ≥99.0% (T)

• Synonyme(s) : Phosphate de sodium secondaire, Hydrogénophosphate de disodium, Hydrogénophosphate de sodium, Phosphate disodique
• Formule linéaire : Na₂HPO₄
• Numéro CAS: 7558-79-4
• Poids moléculaire : 141.96
• Numéro CE : 231-448-7
• Numéro MDL: MFCD00003496
• Code UNSPSC : 12352300
• eCl@ss : 38070211
• ID de substance PubChem : 329763389
• Nomenclature NACRES : NA.21

Propriétés

• Qualité: ACS reagent; puriss. p.a.
• Pureté: ≥99.0% (T)
• Forme: powder (or crystals)
• Impuretés: ≤0.001% total nitrogen (N)
• Perte: ≤0.2% loss on drying, 105 °C
• pH: 8.7-9.3 (25 °C, 50 mg/mL in H₂O)
• pKa (25 °C): (1) 2.15, (2) 6.82, (3) 12.38 (phosphoric acid)
• Traces d'anions: chloride (Cl^-): ≤10 mg/kg; sulfate (SO₄^2-): ≤50 mg/kg
• Traces de cations: Ca: ≤10 mg/kg; Cd: ≤5 mg/kg; Co: ≤5 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤5 mg/kg; K: ≤50 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Ni: ≤5 mg/kg; Pb: ≤5 mg/kg; Zn: ≤5 mg/kg; heavy metals: ≤0.001% (by ICP-OES)
• Chaîne SMILES: [Na+].[Na+].[H]OP([O-])([O-])=O
• InChI: 1S/2Na.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-2
• Clé InChI: BNIILDVGGAEEIG-UHFFFAOYSA-L

Description

Description générale

Sodium phosphate dibasic is a sodium salt of phosphoric acid. It is highly hygroscopic and water-soluble compound used as a texturizer, emulsifier, and buffer. It can also be used as a reagent in water softeners, cleaners, and boiler treatments process.

Sodium phosphate is widely used buffer in molecular biology, biochemistry, and chromatographic studies. It exists in three forms: monobasic (NaH₂PO₄), dibasic (Na₂HPO₄), and tribasic (Na₃PO₄). Monobasic and dibasic forms in varying ratios are commonly used to compose the neutral sodium phosphate buffer solution.

Application

Sodium phosphate dibasic can be used:

• As an efficient and low-cost catalyst for the synthesis of 2-aminochrome by the reaction between aromatic aldehyde, malononitrile, and α- or β-naphthol under solvent-free conditions.
• As a buffer in the synthesis of cyclic, acyclic enones and α, β-unsaturated aldehydes from trimethylsilyl enol ethers by using palladium as a catalyst and oxone as oxidant.
• As an efficient catalyst in the synthesis of 3,4-dihydropyrano[3,2-c] chromenes from aldehydes, malononitrile and 4-hydroxycoumarin.
• As a phosphorous precursor with the phosphoric acid in the synthesis of hydroxyapatite by precipitation method using anionic surfactant SDS (sodium dodefcyl sulfate).

Informations sur la sécurité

• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable