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Azinphos-methyl-(dimethyl-d6)

PESTANAL®, analytical standard

Synonyme(s) :

Azinphos-methyl-d6, Methyltriazotin-d6

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About This Item

Formule empirique (notation de Hill):
C10D6H6N3O3PS2
Poids moléculaire :
323.36
Numéro MDL:
MFCD03701752
Code UNSPSC :
41116107
ID de substance PubChem :
329769564
Nomenclature NACRES :
NA.24

Qualité

analytical standard

Niveau de qualité

100

Gamme de produits

PESTANAL®

Pureté

≥98.0% (HPLC)

Durée de conservation

limited shelf life, expiry date on the label

Application(s)

agriculture

Format

neat

Température de stockage

2-8°C

Chaîne SMILES 

O=C1N(CSP(OC([2H])([2H])[2H])(OC([2H])([2H])[2H])=S)N=NC2=CC=CC=C21

InChI

1S/C10H12N3O3PS2/c1-15-17(18,16-2)19-7-13-10(14)8-5-3-4-6-9(8)11-12-13/h3-6H,7H2,1-2H3/i1D3,2D3

Clé InChI

CJJOSEISRRTUQB-WFGJKAKNSA-N

Description générale

Azinphos-methyl-(dimethyl-d6) is an isotope-labeled analog of the organophosphorus anticholinesterase insecticide azinphos-methyl, wherein dimethoxy protons are substituted by deuterium.

Application

Azinphos-methyl-(dimethyl-d6) may be used as a deuterated internal standard to determine the levels of pesticide analytes in foods, fruits and vegetable matrices by gas chromatography (GC) based techniques.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Skull and crossbonesEnvironment
GHS06,GHS09

Mention d'avertissement

Danger

Mentions de danger

H300 + H330,H311,H317,H410

Classification des risques

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

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Certificats d'analyse (COA)

Lot/Batch Number
BCCK8927
BCCF5823
BCBZ4934
BCBR5914V
BCBR5914

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Effects of carbaryl and azinphos methyl on juvenile rainbow trout (Oncorhynchus mykiss) detoxifying enzymes
Ferrari A, et al.
Pesticide Biochemistry and Physiology, 88(2), 134-142 (2007)
Combined use of a modifier gas generator, analyte protectants and multiple internal standards for effective and robust compensation of matrix effects in gas chromatographic analysis of pesticides
Tsuchiyama T, et al.
Journal of Chromatography A, 1589(3), 122-133 (2019)
Compensation of matrix effects in gas chromatography-mass spectrometry analysis of pesticides using a combination of matrix matching and multiple isotopically labeled internal standards
Tsuchiyama T, et al.
Journal of Chromatography A, 1524(3), 233-245 (2017)
Ali Özcan et al.
Water research, 47(3), 1470-1479 (2013-01-02)
The removal of organophosphorous insecticide azinphos-methyl (AZPM) from water has been investigated by the electro-Fenton method which produces hydroxyl radicals electro-catalytically. The reaction between these radicals and AZPM has led to the oxidation of AZPM up to carbon dioxide and

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