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32917

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Prallethrin

PESTANAL®, analytical standard

Synonyme(s) :

(RS)-2-Methyl-4-oxo-3-prop-2-ynylcyclopent-2-enyl (1RS,3RS;1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate

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About This Item

Formule empirique (notation de Hill):
C19H24O3
Numéro CAS:
23031-36-9
Poids moléculaire :
300.39
Numéro CE :
245-387-9
Numéro MDL:
MFCD03792792
Code UNSPSC :
41116107
ID de substance PubChem :
329754385
Nomenclature NACRES :
NA.24

Qualité

analytical standard

Niveau de qualité

100

Gamme de produits

PESTANAL®

Durée de conservation

limited shelf life, expiry date on the label

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

agriculture
environmental

Format

neat

Température de stockage

2-8°C

Chaîne SMILES 

C\C(C)=C/C1C(C(=O)OC2CC(=O)C(CC#C)=C2C)C1(C)C

InChI

1S/C19H24O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h1,9,14,16-17H,8,10H2,2-6H3

Clé InChI

SMKRKQBMYOFFMU-UHFFFAOYSA-N

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Description générale

Prallethrins are classified under the broad category of pyrethroid insecticides that are utilized in agricultural, domestic and industrial applications. They are typically used for protection against mosquitoes, cockroaches as well as other insects.

Application

Prallethrin may be used as an analytical reference standard for the determination of the analyte in:
  • Sediment samples by dichloromethane (DMC)-based Soxhlet extraction and high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS).
  • Domestic wastewater samples by ultrasound-assisted dispersive liquid–liquid microextraction (UA-DLLME) combined with capillary GC.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Skull and crossbonesEnvironment
GHS06,GHS09

Mention d'avertissement

Danger

Mentions de danger

H302,H331,H410

Classification des risques

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

282.2 °F - closed cup

Point d'éclair (°C)

139 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
BCCJ4484
BCCD7583
BCBZ9640
BCBW3514
SZBF106XV

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Y Tomigahara et al.
Xenobiotica; the fate of foreign compounds in biological systems, 24(9), 839-852 (1994-09-01)
1. Two major metabolites of 14C-labelled (4S,1R)-trans-Etoc[(S)-2-methyl-4-oxo-3-(2-propynyl)cyclopent-2-enyl (1R)-trans-chrysanthemate] were purified using a combination of chromatographic techniques and identified by spectroanalysis (nmr(HMBC) and FAB-, TSP-MS). These were established as new types of S-linked conjugates (sulphonic acid and mercapturic acid types). 2.
Emmanuel M Bhaskar et al.
Journal of medical toxicology : official journal of the American College of Medical Toxicology, 6(1), 27-30 (2010-03-03)
Pyrethroids are common household insecticides. Even though they are less toxic to humans, reports of accidental and suicidal poisoning are not uncommon. Cardiotoxicity due to pyrethroid poisoning is rare. We report a case of cardiac conduction disturbance due to a
C H Schaefer et al.
Journal of the American Mosquito Control Association, 6(4), 621-624 (1990-12-11)
Two new pyrethroids, ETOC and lambdacyhalothrin, showed considerable promise against organophosphorus-resistant adults of Culex tarsalis in laboratory tests. In field trials using nonthermal aerosols, applications of both compounds resulted in effective swaths of up to one-half mile. At the highest
Pyrethroids, pyrethrins, and piperonyl butoxide in sediments by high-resolution gas chromatography/high-resolution mass spectrometry.
Woudneh MB and Oros DR
Journal of Chromatography A, 1135(1), 71-77 (2006)
T Seki et al.
The Journal of toxicological sciences, 12(4), 397-428 (1987-11-01)
d.d-T80-prallethrin, a pyrethroid insecticide for sanitary use, was administered to Crj : CD (Sprague Dawley) rats at concentrations of 120, 600 or 3,000 ppm in diet for one year to assess the chronic toxicity potential and the reversibility. The summarized
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