901221
1-Fluoro-3-isopropoxybenzene
≥95%
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About This Item
Formule empirique (notation de Hill):
C9H11FO
Numéro CAS:
Poids moléculaire :
154.18
Numéro MDL:
Code UNSPSC :
12352200
Produits recommandés
Essai
≥95%
Forme
liquid
Groupe fonctionnel
fluoro
InChI
1S/C9H11FO/c1-7(2)11-9-5-3-4-8(10)6-9/h3-7H,1-2H3
Clé InChI
INDGWZOOYLDIPO-UHFFFAOYSA-N
Application
Autres remarques
- Mechanistic insight leads to a ligand which facilitates the palladium-catalyzed formation of 2-(hetero)arylaminooxazoles and 4-(hetero)arylaminothiazoles
- Diastereoselective Syntheses of (3R*,4R*)- and (3R*,4S*)-4-Aryl-3-methyl-4-piperidinemethanol and Fluoro Analogues
- Solvent-controlled leaving-group selectivity in aromatic nucleophilic substitution
Code de la classe de stockage
10 - Combustible liquids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
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Solvent-controlled leaving-group selectivity in aromatic nucleophilic substitution.
Hintermann L, et al.
Organic Letters, 10(21), 4859-4862 (2008)
Esben P K Olsen et al.
Angewandte Chemie (International ed. in English), 56(35), 10569-10572 (2017-06-13)
By using mechanistic insight, a new ligand (EPhos) for the palladium-catalyzed C-N cross-coupling between primary amines and aryl halides has been developed. Employing an isopropoxy group at the C3-position favors the C-bound isomer of the ligand-supported palladium(II) complexes and leads
Mechanistic Insight Leads to a Ligand Which Facilitates the Palladium?Catalyzed Formation of 2?(Hetero) Arylaminooxazoles and 4?(Hetero) Arylaminothiazoles.
Olsen E P, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 129(35), 10705-10708 (2017)
Sébastien Schmitt et al.
The Journal of organic chemistry, 78(3), 1222-1229 (2013-01-10)
Two concise and high-yielding diastereoselective syntheses of 4-aryl-3-methyl-4-piperidinemethanols were realized from 1,3-dimethyl-4-piperidinone. The key reactions to control the C3-C4 relative stereochemistry were the alkoxymethylation of a metalloenamine generated from 4-aryl-3-methyl-1,2,3,6-tetrahydropyridine that afforded the (3R*,4S*)-form and the nucleophilic substitution of a
Lukas Hintermann et al.
Organic letters, 10(21), 4859-4862 (2008-10-10)
A solvent-controlled inversion of leaving group ability allows selective access to either of two internal substitution products in S(N)Ar reactions of substrates with competing leaving groups. Application of this principle in a selective synthesis of the highly functionalized xanthone core
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