735809

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]carbonylchlorohydridoruthenium(II)

• Synonyme(s) : Milstein Catalyst Precursor, [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
• Formule empirique (notation de Hill): C₂₀H₃₆ClN₂OPRu
• Numéro CAS: 863971-62-4
• Poids moléculaire : 488.01
• Numéro MDL: MFCD16038117
• Code UNSPSC : 12352300
• ID de substance PubChem : 329765059
• Nomenclature NACRES : NA.22

Propriétés

• Forme: powder
• Pertinence de la réaction: core: ruthenium; reagent type: catalyst
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Autre catégorie plus écologique: Aligned,
• Chaîne SMILES: Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
• InChI: 1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
• Clé InChI: RZCAJPSOQUIHSH-UHFFFAOYSA-M

Description

Description générale

May contain up to 10% acetone and/or THF.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

Informations sur la sécurité

• Pictogrammes: GHS08,GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H319,H351
• Conseils de prudence: P281 - P305 + P351 + P338
• Classification des risques: Carc. 2 - Eye Irrit. 2
• Risques supp: EUH019
• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable