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703214

Sigma-Aldrich

Di-tetrabutylammonium cis-bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II)

95% (NMR)

Synonyme(s) :

Greatcell Solar®, N-719 dye

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1 G
561,00 €

561,00 €


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1 G
561,00 €

About This Item

Formule empirique (notation de Hill):
C58H86N8O8RuS2
Numéro CAS:
Poids moléculaire :
1188.55
Numéro MDL:
Code UNSPSC :
12352103
ID de substance PubChem :
Nomenclature NACRES :
NA.23

561,00 €


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Devis pour commande en gros

Niveau de qualité

Essai

95% (NMR)

Forme

powder

Composition

Dye content, ≥90% HPLC

Pf

250-260 °C

λmax

534, 393, 313 nm (lit.)

Chaîne SMILES 

S=C=N[Ru]N=C=S.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.OC(=O)c1ccnc(c1)-c2cc(ccn2)C([O-])=O.OC(=O)c3ccnc(c3)-c4cc(ccn4)C([O-])=O

InChI

1S/2C16H36N.2C12H8N2O4.2CNS.Ru/c2*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*15-11(16)7-1-3-13-9(5-7)10-6-8(12(17)18)2-4-14-10;2*2-1-3;/h2*5-16H2,1-4H3;2*1-6H,(H,15,16)(H,17,18);;;/q2*+1;;;2*-1;+2/p-2

Clé InChI

MQGCPZMVNHGIPF-UHFFFAOYSA-L

Description générale

Di-tetrabutylammonium cis-bis(isothiocyanato)bis(2,2′-bipyridyl-4,4′-dicarboxylato)ruthenium(II) (N-719 dye) is a ruthenium based polypyridyl mixture used as a photosensitizer. It acts as a medium for effective absorption of photons and transfer of electrons within the electrolytic solar cells.[1][2]

Application

N-719 dye is widely used as a sensitizer that can be coated on indium tin oxide (ITO) substrates by doctor blade technique, with different photoanode materials like titanium oxide (TiO2),[3][4][5] zinc oxide (ZnO),[6][7] and gold nanourchin[8] for dye sensitized solar cell (DSSC) applications.

Informations légales

Product of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Greatcell Solar is a registered trademark of Greatcell Solar

Pictogrammes

Health hazard

Mention d'avertissement

Danger

Mentions de danger

Conseils de prudence

Classification des risques

Resp. Sens. 1

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Ruthenium sensitizers and their applications in dye-sensitized solar cells
Hara K and Koumura N
International Journal of Photoenergy (2012)
Au nanoparticle-decorated urchin-like TiO2 hierarchical microspheres for high performance dye-sensitized solar cells
Li Y, et al.
Electrochimica Acta, 293(2), 230-239 (2019)
Nanoforest of hydrothermally grown hierarchical ZnO nanowires for a high efficiency dye-sensitized solar cell
Ko SH, et al.
Nano Letters, 11(2), 666-671 (2011)
Efficient dye-sensitized solar cells from mesoporous zinc oxide nanostructures sensitized by N719 dye
Kumara GRA, et al.
Journal of Semiconductors, 39(3), 033005-033005 (2018)
Enhancing near-infrared solar cell response using upconverting transparentceramics
Liu M, et al.
Solar Energy Materials and Solar Cells, 95(2), 800-803 (2011)

Articles

Dye-sensitized solar cells directly convert sunlight to electricity

Dye-sensitized solar cells (DSSCs) attract attention for high performance and potential low-cost production in solar energy.

Operation principle and market dominance of single crystalline silicon solar cells.

Dye-sensitized solar cells (DSCs) are 3rd generation solar cells combining the promise of high efficiency with low production costs.

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Questions

1–4 of 4 Questions  
  1. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  2. What are the advantages of dye solar cells?

    1 answer
    1. Dye solar cells (DSCs) are 3rd generation solar cells with the promise of high efficiency combined with low production costs.

      Helpful?

  3. What are the disadvantages of dye solar cells?

    1 answer
    1. The major disadvantage to the dye solar cell design is the use of a liquid electrolyte, which has temperature stability issues. The electrolyte can freeze at low temperatures and expand at higher temperatures.  It the electrolytes freezes, power production would cease, and it could potentially lead to physical damage.  If the liquid expands at higher temperatures, sealing the panels would be difficult.

      Helpful?

  4. What can cause degradation of the dye solar cell?

    1 answer
    1. Dye solar cells degrade from ultraviolet radiation.  For this reason, the barrier may include UV stabilizers and/or UV absorbing luminescent chromophores (which emit at longer wavelengths) and antioxidants to protect and improve the efficiency of the cell.

      Helpful?

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