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437867

Sigma-Aldrich

Copper(II) bromide

99.999% trace metals basis

Synonyme(s) :

Cupric bromide

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About This Item

Formule linéaire :
CuBr2
Numéro CAS:
7789-45-9
Poids moléculaire :
223.35
Numéro CE :
232-167-2
Numéro MDL:
MFCD00010970
Code UNSPSC :
12352302
ID de substance PubChem :
24867403
Nomenclature NACRES :
NA.23

70,00 €

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Qualité

for analytical purposes

Essai

99.999% trace metals basis

Forme

solid

Impuretés

≤15.0 ppm Trace Metal Analysis

Pf

498 °C (lit.)

Densité

4.77 g/mL at 25 °C (lit.)

Application(s)

battery manufacturing

Chaîne SMILES 

Br[Cu]Br

InChI

1S/2BrH.Cu/h2*1H;/q;;+2/p-2

Clé InChI

QTMDXZNDVAMKGV-UHFFFAOYSA-L

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Catégories apparentées

Description générale

Copper bromide is a monoclinic crystalline material. It is soluble in water, alcohol and acetone. It may be synthesized by neutralizing oxides, carbonates or hydroxides of copper with hydrobromic acid. Another synthesis technique is by oxidizing copper either with bromine water or bromine solutions in alcohol.[1]

Application

Copper bromide may be used as a catalyst in organic reactions and as a brominating agent.[1] Copper catalyzed biotinylation of acetylene terminated poly(ethylene glycol) methyl ether methylacrylate (PEGMEMA) chains has been investigated.[2] Copper dibromide in acetonitrile acts as a catalyst in the interconversion of acetals to bis(methoxyphenyl)methyl (BMPM) ethers.[3] It has been used as a catalyst in the intramolecular decarboxylative functionalization of α-carbonyl to yield a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins.[4] Poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been reportedly doped with CuBr2 to act as hole transport layer (HTL) in polymer solar cells(PSCs). Doping increase the conductivity and thereby increasing the device power conversion efficiency of PSCs. [5]

Pictogrammes

CorrosionExclamation markEnvironment
GHS05,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H302,H314,H410

Classification des risques

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

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Zhiqiang Zhao et al.
ACS applied materials & interfaces, 7(3), 1439-1448 (2014-12-24)
Copper(II) bromide (CuBr2) salt has been applied to dope poly(3,4-ethylene dioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) as the hole transport layer (HTL) in polymer solar cells (PSCs), improving dramatically the conductivity of PEDOT:PSS film and consequently the device power conversion efficiency (PCE). Under the
Copper(ii) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins.
Zhang WL, et al.
Organic & Biomolecular Chemistry, 13(12), 3602-3609 null
Copper(II) bromide as an efficient catalyst for acetal to bisarylmethyl ether interconversion
Mezaache R, et al.
Tetrahedron Letters, 55(52), 7167-7171 (2014)
Richardson HW
Handbook of Copper Compounds and Applications null
Gavin T Knight et al.
Journal of visualized experiments : JoVE, 92(92), e52186-e52186 (2014-11-20)
In tissue engineering, it is desirable to exhibit spatial control of tissue morphology and cell fate in culture on the micron scale. Culture substrates presenting grafted poly(ethylene glycol) (PEG) brushes can be used to achieve this task by creating microscale
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