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Sigma-Aldrich

Manganese(III) acetate dihydrate

97%

Synonyme(s) :

Manganese triacetate dihydrate

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About This Item

Formule linéaire :
(CH3COO)3Mn · 2H2O
Numéro CAS:
19513-05-4
Poids moléculaire :
268.10
Numéro Beilstein :
3732626
Numéro CE :
213-602-5
Numéro MDL:
MFCD00150022
Code UNSPSC :
12352103
ID de substance PubChem :
24852919
Nomenclature NACRES :
NA.23

Pureté

97%

Forme

powder or chunks

Pertinence de la réaction

core: manganese

Chaîne SMILES 

O.O.CC(=O)O[Mn](OC(C)=O)OC(C)=O

InChI

1S/3C2H4O2.Mn.2H2O/c3*1-2(3)4;;;/h3*1H3,(H,3,4);;2*1H2/q;;;+3;;/p-3

Clé InChI

ONJSLAKTVIZUQS-UHFFFAOYSA-K

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Catégories apparentées

Description générale

Manganese(III) acetate dihydrate is a coordination compound of manganese in the +3 oxidation state, exhibiting moderate solubility in water and acetic acid. It is used as a precursor for synthesizing manganese oxides and other manganese-containing materials. These materials have applications in batteries, catalysis, and other energy-related technologies. Additionally, it is also used as a mild and selective oxidizing agent in organic synthesis.

Application

Manganese(III) acetate dihydrate can be used as:      
  • A precursor in the synthesis of manganese oxide (Mn3O4) nanostructures, which are employed as anode materials in lithium-ion batteries.
  • A manganese source in the sol-gel synthesis of Mn-doped ZnO thin films. The incorporation of manganese ions into the ZnO lattice is essential for modifying the electronic and optical properties of the films.
  • A precursor for the synthesis of manganese oxide nanoparticles using a sol-gel process. These nanoparticles are evaluated for their performance in supercapacitor applications.     
  • A mild and selective oxidizing agent. Catalyzes allylic oxidation of a variety of alkenes in the presence of tert-butylhydroperoxide. Reagent used for radical cyclizations and α-keto-acetoxylation.

Forme physique

Crystallographic evidence suggests this material is an oxo-centered triangle of Mn(III) with bridging acetates having the molecular formula: Mn3O(OAc)9 · 6H2O.

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

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Tony K M Shing et al.
Organic letters, 8(14), 3149-3151 (2006-06-30)
Manganese(III) acetate catalyzed allylic oxidation of alkenes to the corresponding enones was investigated, showing excellent regioselectivity and chemoselectivity (functional group compatibility). Delta(5)-Steroids were transformed into bioactive Delta(5)-en-7-ones under a nitrogen atmosphere, whereas simple alkenes were converted into the corresponding enones
The Journal of Organic Chemistry, 62, 6978-6978 (1997)
Ao Qian et al.
Environmental science & technology, 53(10), 5768-5777 (2019-04-12)
Dissolved Mn(III) species have recently been recognized as a significant form of Mn in redox transition zones, but their speciation, stability, and reactivity are poorly understood. Besides acting as the intermediate for Mn redox chemistry, Mn(III) can undergo disproportionation producing
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 36, 2042-2042 (1980)
Chaoyun Ying et al.
Water research, 187, 116420-116420 (2020-09-26)
Manganese(IV) oxides, and more especially birnessite, rank among the most efficient metal oxides for As(III) oxidation and subsequent sorption, and thus for arsenic immobilization. Efficiency is limited however by the precipitation of low valence Mn (hydr)oxides at the birnessite surface
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