14765
Thallium(I) acetate
purum, ≥97.0%
Synonym(s):
TlOAc, Acetic acid thallium(I) salt
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About This Item
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grade
purum
Quality Level
Assay
≥97.0%
form
solid
reaction suitability
core: thallium
reagent type: catalyst
SMILES string
CC(=O)O[Tl]
InChI
1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
InChI key
HQOJMTATBXYHNR-UHFFFAOYSA-M
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General description
Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.
Application
- Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The Journal of Organic Chemistry, 48, 2021-2021 (1983)
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
Tetrahedron Letters, 33, 7789-7789 (1992)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
ECS Transactions, 13(20), 7-7 (2008)
Journal of applied toxicology : JAT, 16(5), 385-389 (1996-09-01)
A histopathological study, with a light microscope, of experimental neuromyopathy produced by thallotoxicosis was undertaken in 40 newborn Wistar rats. Treatment consisted of a single i.p. injection of an aqueous solution of 16 mg kg-1 thallium(I) acetate 1 day after
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