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A1002

Sigma-Aldrich

Acetaldehyde oxime, mixture of syn and anti

99%

Synonym(s):

Acetaldoxime

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About This Item

Linear Formula:
CH3CH=NOH
CAS Number:
107-29-9
Molecular Weight:
59.07
Beilstein:
1209252
EC Number:
203-479-6
MDL number:
MFCD00002124
UNSPSC Code:
12352100
PubChem Substance ID:
24890491
NACRES:
NA.22

Assay

99%

form

liquid

refractive index

n20/D 1.426 (lit.)

bp

115 °C (lit.)

density

0.969 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C\C=N\O

InChI

1S/C2H5NO/c1-2-3-4/h2,4H,1H3/b3-2+

InChI key

FZENGILVLUJGJX-NSCUHMNNSA-N

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Related Categories

Pictograms

FlameSkull and crossbones
GHS02,GHS06

Signal Word

Danger

Hazard Statements

H226,H302,H319,H331,H412

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

104.0 °F - open cup

Flash Point(C)

40 °C - open cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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M D Mikkelsen et al.
The Journal of biological chemistry, 275(43), 33712-33717 (2000-08-03)
Glucosinolates are natural plant products known as flavor compounds, cancer-preventing agents, and biopesticides. We report cloning and characterization of the cytochrome P450 CYP79B2 from Arabidopsis. Heterologous expression of CYP79B2 in Escherichia coli shows that CYP79B2 catalyzes the conversion of tryptophan
Michael J Prival
Mutation research, 537(2), 201-208 (2003-06-06)
Acetaldehyde oxime was found to induce more revertants in Salmonella typhimurium strain TA1535 than in TA100 in the absence of S9 metabolic activation. TA100 was originally constructed from TA1535 by the addition of the plasmid pKM101, carrying mucAB which generally
Katsuaki Kobayashi et al.
Chembiochem : a European journal of chemical biology, 7(12), 2004-2009 (2006-09-30)
Phenylacetaldoxime dehydratase from Bacillus sp. OxB-1 (OxdB) contains a heme that acts as the active site for the dehydration reaction of aldoxime. Ferrous heme is the active form, in which the heme is five coordinate with His282 as a proximal
Rong-Zhen Liao et al.
The journal of physical chemistry. B, 116(31), 9396-9408 (2012-07-18)
Aldoxime dehydratase is a heme-containing enzyme that utilizes the ferrous rather than the ferric ion to catalyze the synthesis of nitriles by dehydration of the substrate. We report a theoretical study of this enzyme aimed at elucidating its catalytic mechanism
Kazunobu Konishi et al.
The Journal of biological chemistry, 279(46), 47619-47625 (2004-09-02)
Aldoxime dehydratase (OxdA), which is a novel heme protein, catalyzes the dehydration of an aldoxime to a nitrile even in the presence of water in the reaction mixture. The combination of site-directed mutagenesis of OxdA (mutation of all conserved histidines
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