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635936

Sigma-Aldrich

N-Cyclohexylhydroxylamine

Synonym(s):

N-Hydroxycyclohexanamine, N-Hydroxycyclohexylamine

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About This Item

Linear Formula:
C6H11NHOH
CAS Number:
2211-64-5
Molecular Weight:
115.17
EC Number:
218-650-0
MDL number:
MFCD00021287
UNSPSC Code:
12352100
PubChem Substance ID:
24882743
NACRES:
NA.22

form

solid

mp

139-140 °C (lit.)

storage temp.

−20°C

SMILES string

ONC1CCCCC1

InChI

1S/C6H13NO/c8-7-6-4-2-1-3-5-6/h6-8H,1-5H2

InChI key

GUQRKZPMVLRXLT-UHFFFAOYSA-N

Related Categories

General description

N-Cyclohexylhydroxylamine is formed as one of the by-products during the hydrogenation of nitrocyclohexane to the corresponding cyclohexanone oxime catalyzed by palladium/carbon nanotubes.

Application

Reactant for:
  • Aldehyde-catalyzed intermolecular hydroamination
  • Condensation reactions
  • Preparation of cyclin-dependent kinase inhibitors selective for multiple cyclin-dependent kinases for potential use as antitumor agents
  • Preparation of hydroxyurea derivatives as small molecule bradykinin B1 receptor antagonists

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H318

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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"Hydrogenation of nitrocyclohexane to cyclohexanone oxime over Pd/CNT catalyst under mild conditions"
Liao G-H, et al.
Catalysis Communications, 19, 80-84 (2012)

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