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Sigma-Aldrich

Palladium on carbon

Evonik NOBLYST® P1173 10% Pd

Synonym(s):

Pd/C

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1 G
€41.20
10 G
€185.00
50 G
€879.00
250 G
€3,340.00

About This Item

Linear Formula:
Pd
Molecular Weight:
106.42
MDL number:
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22

€41.20


In StockDetails


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Quality Level

contains

~50% water

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

extent of labeling

10 wt. % loading (dry basis)

weight

Unit weight excludes weight of water

matrix

activated carbon, wet support

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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General description

Pd/C is used as a catalyst for hydrogenation of ketones, alkynes, alkenes, nitriles, azides, imines, nitro groups, and heterocyclic aromatic compounds.[1]

Application

Catalyst for:
  • Stille reaction
  • Hydrogenation reactions
  • Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions
  • Deoxygenation
  • Oxidation reactions
  • Coupling reactions
Recent journal articles also use Pd/C for the following:
  • Transfer hydrogenation of aromatic nitro compounds to anilines in the presence of methanol as a green reductant.[2]
  • N-Methylation of nitroarenes and amines.[3]
  • Aminocarbonylation of aryl iodides to synthesize primary amides.[4]
  • Direct C-2 arylation of indoles with arylboronic acids.[5]
  • Synthesis of polyamides via carbonylation polycondensation reaction.[6]
Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Legal Information

Noblyst is a registered trademark of Evonik Degussa GmbH

related product

Product No.
Description
Pricing

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Synthesis of polyamides using palladium-on-carbon (Pd/C) as a heterogeneous, reusable and ligand-free catalytic system
Satapathy A, et al.
Royal Society of Chemistry Advances, 5, 93773-93778 (2015)
Commercial Pd/C-catalyzed N-methylation of nitroarenes and amines using methanol as both C1 and H2 source
Goyal V, et al.
The Journal of Organic Chemistry, 84, 15389-15398 (2019)
Direct C-H bond activation: palladium-on-carbon as a reusable heterogeneous catalyst for C-2 arylation of indoles with arylboronic acids
Bhattacharjee P, et al.
New. J. Chem., 44, 7675-7682 (2020)
Palladium on Carbon
Anthony OK and Ichiro S
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Pd/C-catalyzed transfer hydrogenation of aromatic nitro compounds using methanol as a hydrogen source
Goyal V, et al.
Journal of the Indian Chemical Society, 98, 100014-100014 (2021)

Articles

An application guide to help you select the most suitable heterogeneous catalysts for diverse synthetic applications.

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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