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17354

Sigma-Aldrich

2-(Boc-amino)ethyl bromide

≥97.0% (GC)

Synonym(s):

N-Boc-2-bromoethyl-amine, tert-Butyl N-(2-bromoethyl)carbamate

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1 G
€62.60
5 G
€146.00

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1 G
€62.60
5 G
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About This Item

Linear Formula:
BrCH2CH2NHCO2C(CH3)3
CAS Number:
39684-80-5
Molecular Weight:
224.10
Beilstein:
2325117
MDL number:
MFCD02683428
UNSPSC Code:
12352101
PubChem Substance ID:
57647641
NACRES:
NA.22

€62.60

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Quality Level

200

Assay

≥97.0% (GC)

reaction suitability

reagent type: cross-linking reagent

mp

30-32 °C (lit.)

functional group

Boc
amine
bromo

shipped in

wet ice

storage temp.

−20°C

SMILES string

BrCCNC(OC(C)(C)C)=O

InChI

1S/C7H14BrNO2/c1-7(2,3)11-6(10)9-5-4-8/h4-5H2,1-3H3,(H,9,10)

InChI key

TZRQZPMQUXEZMC-UHFFFAOYSA-N

Related Categories

General description

2-(Boc-amino)ethyl bromide is used in organic synthesis to introduce Boc-protective group and enable the synthesis of various compounds like peptides.[1]

Other Notes

Building block for preparing fluorinated spacers having nucleophilic and electrophilic termini[2]; synthesis of a biphenyl linker[3]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBK0278V
1371897V
1371897
1369927
BCBJ2721V

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Convergent Synthesis and Diversity of Amino Acid Based Dendrimers
Arwin J B, et al.
European Journal of Organic Chemistry, 1903-1915 (2001)
L. Chen et al.
Tetrahedron Letters, 39, 3627-3627 (1998)
P. Mougenot et al.
The Journal of Organic Chemistry, 61, 408-408 (1996)
Jinping Cheng et al.
International journal of nanomedicine, 6, 2007-2021 (2011-10-07)
Carbon nanotubes have shown broad potential in biomedical applications, given their unique mechanical, optical, and chemical properties. In this pilot study, carbon nanotubes have been explored as multimodal drug delivery vectors that facilitate antiangiogenic therapy in zebrafish embryos. Three different
Marina Marinović et al.
Molecules (Basel, Switzerland), 25(19) (2020-09-27)
Harmicines represent hybrid compounds composed of β-carboline alkaloid harmine and cinnamic acid derivatives (CADs). In this paper we report the synthesis of amide-type harmicines and the evaluation of their biological activity. N-harmicines 5a-f and O-harmicines 6a-h were prepared by a

Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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