762415
2-Azido-1,3-dimethylimidazolinium hexafluorophosphate
97%
Synonym(s):
2-Azido-4,5-dihydro-1,3-dimethyl-1H-imidazolium hexafluorophosphate
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About This Item
Empirical Formula (Hill Notation):
C5H10F6N5P
CAS Number:
Molecular Weight:
285.13
MDL number:
UNSPSC Code:
12352202
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
solid
reaction suitability
reaction type: click chemistry
availability
available only in USA
mp
205-210 °C
storage temp.
−20°C
SMILES string
F[P-](F)(F)(F)(F)F.CN1CC[N+](C)=C1N=[N+]=[N-]
InChI
1S/C5H10N5.F6P/c1-9-3-4-10(2)5(9)7-8-6;1-7(2,3,4,5)6/h3-4H2,1-2H3;/q+1;-1
InChI key
SKAIRSILDPLHCV-UHFFFAOYSA-N
Application
Efficient diazo transfer reagent for the preparation of azides from primary amines. An alternative to tosyl azide with an easier-to-separate water soluble by-product.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Self-react. C
Storage Class Code
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Customers Also Viewed
Direct Synthesis of Organic Azides from Primary Amines with 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate.
Kitamura, M.
European Journal of Organic Chemistry, 458-462 (2011)
Mitsuru Kitamura, et al
Synthesis, 7, 1037-1044 (2011)
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