Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
372870
Iron(II) chloride
98%
Synonym(s):
Ferrous chloride, Iron dichloride
About This Item
Recommended Products
Quality Level
Assay
98%
form
powder
reaction suitability
core: iron
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)
greener alternative product characteristics
Catalysis
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mp
677 °C (lit.)
density
3.16 g/mL at 25 °C (lit.)
greener alternative category
, Aligned
SMILES string
Cl[Fe]Cl
InChI
1S/2ClH.Fe/h2*1H;/q;;+2/p-2
InChI key
NMCUIPGRVMDVDB-UHFFFAOYSA-L
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General description
Application
- The preparation of Grignard compounds, such as 1-naphthylmagnesium chloride.[1]
- The selective oxidation of 2,4,6-trimethylphenol (2,4,6-TMP) to 3,5-dimethyl-4-hydroxybenzaldehyde (DMHB) in the presence of acetoxime.[2]
- Raney-type catalysts modified with FeCl2 show enhanced selective hydrogenation of an α,β-unsaturated aldehyde to an unsaturated alcohol.[3]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
does not flash
Flash Point(C)
does not flash
Personal Protective Equipment
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Protocols
We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.
We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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