335363

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II)

• Synonym(s): (1,3-dppp)NiCl₂, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, Ni(dppp)Cl₂
• Linear Formula: [(C₆H₅)₂P(CH₂)₃P(C₆H₅)₂]NiCl₂
• CAS Number: 15629-92-2
• Molecular Weight: 542.04
• MDL number: MFCD00015318
• UNSPSC Code: 12161600
• PubChem Substance ID: 24860309
• NACRES: NA.22

Properties

• form: powder
• reaction suitability: core: nickel; reaction type: Cross Couplings; reagent type: catalyst
• mp: 213 °C (dec.) (lit.)
• SMILES string: Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4
• InChI: 1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
• InChI key: ZBQUMMFUJLOTQC-UHFFFAOYSA-L

Description

Application

Catalyst for:

• Synthesis of block-copolythiophenes
• Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
• Solid state metathesis polycondensation
• Polymerization of poly(3-alkoxythiophene)s
• Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
• Transfer condensation polymerization of conjugated polymers

[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method.

Safety Information

• Pictograms: GHS08,GHS07
• Signal Word: Danger
• Hazard Statements: H315,H317,H319,H334,H335,H350
• Precautionary Statements: P202 - P261 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves