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114693

Sigma-Aldrich

1-Nitroso-2-naphthol

97%

Synonym(s):

1-Nitroso-2-hydroxynaphthalene

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About This Item

Linear Formula:
ONC10H6OH
CAS Number:
131-91-9
Molecular Weight:
173.17
Colour Index Number:
10005
Beilstein:
776947
EC Number:
205-043-0
MDL number:
MFCD00003884
UNSPSC Code:
12352100
PubChem Substance ID:
24847189
NACRES:
NA.22
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Assay

97%

form

solid

mp

106-108 °C (dec.) (lit.)

functional group

C-nitroso
nitroso

SMILES string

Oc1ccc2ccccc2c1N=O

InChI

1S/C10H7NO2/c12-9-6-5-7-3-1-2-4-8(7)10(9)11-13/h1-6,12H

InChI key

YXAOOTNFFAQIPZ-UHFFFAOYSA-N

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Application

1-Nitroso-2-naphthol is the chelating ion-exchanger in the synthesis of alumina adsorbents that are of acidic, basic and neutral nature. It is used for the removal and preconcentration of Pb(II), Cu(II), Cr(III) from waste, as well as drinking water[1]. It is also used in the preconcentration of cobalt using C(18) microcolumn with flow injection that is coupled to a flame atomic absorption spectrometry (FI-FAAS) system[2].
1-Nitroso-2-naphthol is used in the preparation of 1-nitroso-2-naphthol-sodium nitrite reagent[3].

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H317,H319,H341

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBH0889
STBG9593
STBF1603V
STBF0155V
STBD2655V

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Yingxue Ye et al.
Talanta, 57(5), 945-951 (2008-10-31)
The suitability of 1-nitroso-2-naphthol (NN) as a complexing agent for on-line preconcentration of cobalt using C(18) microcolumn with FI-FAAS system has been tested. Various parameters affecting the complex formation and its elution were optimized. Reagent solution (2.5x10(-3) mol l(-1)) and
Fluorometric measurement of tyrosine in serum and plasma.
J A Ambrose
Clinical chemistry, 20(4), 505-510 (1974-04-01)
C F Burrows et al.
Journal of the American Veterinary Medical Association, 183(3), 318-322 (1983-08-01)
The nitrosonapthol test, which qualitatively measures urinary excretion of 4-hydroxyphenylacetic acid and related compounds, was evaluated as a screening test for small intestinal disease in 60 dogs with chronic diarrhea. Test results were positive in 8 of 13 dogs with
[A modified method of determination of bound 5-hydroxyindoleacetic acid in the urine].
N G Shafranova et al.
Laboratornoe delo, (7)(7), 25-26 (1983-01-01)
N-acetyl-L-cysteine: an alternative to 2-mercaptoethanol in the reduction of Udenfriend's chromophore used for the determination of urinary 5-hydroxyindoleacetic acid.
M Zouheir Habbal
Clinica chimica acta; international journal of clinical chemistry, 130(2), 251-256 (1983-05-30)
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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