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04107

Sigma-Aldrich

Phosphoric acid

puriss., meets analytical specification of Ph. Eur., BP, NF, FCC, 85.0-88.0%

Synonym(s):

Orthophosphoric acid

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About This Item

Linear Formula:
H3PO4
CAS Number:
7664-38-2
Molecular Weight:
98.00
Beilstein:
1921286
EC Number:
231-633-2
MDL number:
MFCD00011340
UNSPSC Code:
12352106
PubChem Substance ID:
329747880
NACRES:
NA.21

vapor density

3.4 (vs air)

Quality Level

200

vapor pressure

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

grade

puriss.

Assay

85.0-88.0%

form

liquid

quality

meets analytical specification of Ph. Eur., BP, NF, FCC

impurities

alkali phosphates, in accordance
 residual solvents, in accordance
 substance precip. by Ammonia, in accordance
≤0.0005% heavy metals (as Pb)
≤0.001% volatile acids (as CH3COOH)

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤5 mg/kg
fluoride (F-): ≤5 mg/kg
nitrate (NO3-): ≤5 mg/kg
nitrate (NO3-): in accordance
phosphite, hypophosphite (as H3PO3): ≤30 mg/kg
phosphite, hypophosphite (as H3PO3): in accordance
sulfate (SO42-): ≤50 mg/kg
sulfate (SO42-): in accordance

cation traces

As: ≤2 mg/kg
Cd: ≤3 mg/kg
Cu: ≤10 mg/kg
Fe: ≤10 mg/kg
Hg: ≤1 mg/kg
Pb: ≤3 mg/kg
Zn: ≤10 mg/kg

suitability

passes test for appearance of solution

SMILES string

OP(O)(O)=O

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

Gene Information

human ... SRC(6714)

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Other Notes

Concentrated phosphoric acid is approx. 85% H3PO4 (aqueous).
The article number 04107-4X2.5L will be discontinued. Please order the single bottle 04107-2.5L which is physically identical with the same exact specifications.
The article number 04107-6X1L will be discontinued. Please order the single bottle 04107-1L which is physically identical with the same exact specifications.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H290,H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Internal versus external surface active sites in ZSM-5 zeolite: Part 1. Fries rearrangement catalyzed by modified and unmodified H3PO4/ZSM-5.
Ghiaci M, et al.
Applied Catalysis A: General, 298, 32-39 (2006)
J M Fujitaki et al.
Biochemistry, 20(12), 3658-3664 (1981-06-09)
Phosphorus-31 nuclear magnetic resonance (31P NMR) is used to investigate acid-labile phosphorylation of histone H4. 31P NMR detects phosphorylated histidine residues in in vitro enzymatically phosphorylated H4. The source of kinase is nuclei from either regenerating rat liver or Walker-256
P Meneses et al.
Journal of lipid research, 29(5), 679-689 (1988-05-01)
The common phospholipids from biological sources were quantitated using phosphorus-31 nuclear magnetic resonance (NMR) spectroscopy in conjunction with an analytical reagent composed of two parts: 1) 2 ml of reagent chloroform in which was dissolved 0.01-100 mg of crude tissue
D S Marinier et al.
Journal of lipid research, 29(9), 1237-1243 (1988-09-01)
In order to study the lipid composition of human white matter, we have developed a 31P NMR spectroscopy method, which allows the determination and quantitation of the main phospholipids found in biological membranes. The technique is based upon the use
Li Yan Chan et al.
The Journal of organic chemistry, 78(17), 8826-8832 (2013-08-07)
A simple and efficient method is developed for Pd-catalyzed ortho-acetoxylation using organophosphates, namely, benzylic phosphonic and aryl phosphoric monoacids, as the directing group.
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