If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
B56412
Bromoacetyl bromide
≥98%
Synonym(s):
α-Bromoacetyl bromide, 2-Bromoacetyl bromide, Monobromoacetyl bromide
About This Item
Recommended Products
vapor pressure
3.8 mmHg ( 25 °C)
Assay
≥98%
form
liquid
refractive index
n20/D 1.547 (lit.)
bp
147-150 °C (lit.)
density
2.317 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
BrCC(Br)=O
InChI
1S/C2H2Br2O/c3-1-2(4)5/h1H2
InChI key
LSTRKXWIZZZYAS-UHFFFAOYSA-N
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General description
Application
- Amines to azido acetamides.[2]
- p-Arsanilic acid to 4-(2-bromoacetylamino)benzenearsonic acid, a precursor to 4-(N-(S-penicillaminylacetyl)amino)phenylarsonous acid (PENAO), a metal-based drug.[3]
- 3,5-Dimethylphenol to 3,5-dimethylphenyl 2-bromoacetate.[4]
- Cystamine dihydrochloride to N,N′-bis(bromoacetyl) cystamine, a bifunctional quaternizing agent.[5]
It can also be used as a reagent to synthesize imidazolium or piridinium based ionic liquids.[6]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
221.0 °F - closed cup
Flash Point(C)
105 °C - closed cup
Personal Protective Equipment
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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