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723010

Sigma-Aldrich

2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid

98% (HPLC)

Synonym(s):

2-(Dodecylthiocarbonothioylthio)-2-methylpropanoic acid, S-Dodecyl-S′-(α,α′-dimethyl-α′′-acetic acid)trithiocarbonate, DDMAT

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About This Item

Empirical Formula (Hill Notation):
C17H32O2S3
CAS Number:
461642-78-4
Molecular Weight:
364.63
MDL number:
MFCD10698871
UNSPSC Code:
12352100
PubChem Substance ID:
329763968
NACRES:
NA.23

Assay

98% (HPLC)

form

powder

mp

57-63 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C(O)=O

InChI

1S/C17H32O2S3/c1-4-5-6-7-8-9-10-11-12-13-14-21-16(20)22-17(2,3)15(18)19/h4-14H2,1-3H3,(H,18,19)

InChI key

DZFGVGDQHQHOKZ-UHFFFAOYSA-N

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General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization
RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene, acrylate and acrylamide monomers. Chain Transfer Agent (CTA)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Haichao Duan et al.
Nanoscale, 10(26), 12487-12496 (2018-06-22)
Well-dispersed ultrafine palladium nanoparticles supported by reduced graphene oxide functionalized with catechol-terminated thermo-responsive block copolymer (PdNPs@BPrGO) were successfully constructed for highly efficient heterogeneous catalytic reduction. We first synthesized a novel temperature-responsive episulfide-containing double-hydrophilic diblock copolymer, poly(poly(ethylene glycol) methyl ether methacrylate-co-2,3-epithiopropyl
Wenyan Wang et al.
Carbohydrate polymers, 207, 239-245 (2019-01-03)
This study reports on eco-friendly graft polymerization approach for the modification of a cellulosic material via combination between enzymatic catalysis and reversible addition-fragmentation chain transfer polymerization (RAFT). Polyacrylamide (PAM) was polymerized on a cellulosic filter paper via horseradish peroxidase (HRP)-initiated
Jun Akimoto et al.
ACS omega, 4(15), 16344-16351 (2019-10-17)
A thermoresponsive ABA triblock copolymer bearing an aldehyde group on the thermoresponsive A segments was synthesized. The polymer formed a micellar assembly due to the hydrophobic interactions of the thermoresponsive segment above the lower critical solution temperature (LCST). In contrast
Chloé Grazon et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(5), 1156-1165 (2019-02-26)
A new ratiometric fluorescent pH nanosensor is presented. It is based on ultrabright nanoparticles containing two spatially separated fluorophores: BODIPY covalently linked to the polystyrene core and fluorescein grafted to the nanoparticle shell. The nanoparticles comprise a large number (≥2500)
Despoina Giaouzi et al.
Polymers, 12(6) (2020-06-25)
In this work, the synthesis, selective chemical modifications, and self-assembly behavior in aqueous media of a novel poly(2-(dimethylamino)ethyl acrylate)20-b-poly(N-isopropylacrylamide)11-b-poly(oligo ethylene glycol methyl ether acrylate)18 (PDMAEA20-b-PNIPAM11-b-POEGA18) dual-responsive (pH and temperature) and triply hydrophilic amino-based triblock terpolymer are reported. The amine functional
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Protocols

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

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