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668796

Sigma-Aldrich

(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine

97%

Synonym(s):

(S)-(+)-1-AminoTetralin, (S)-(+)-1-Aminotetraline

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About This Item

Linear Formula:
(C10H11)NH2
CAS Number:
23357-52-0
Molecular Weight:
147.22
Beilstein:
2360279
MDL number:
MFCD00671630
UNSPSC Code:
12352116
PubChem Substance ID:
24885002
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.565

bp

250 °C

density

1.010 g/mL at 25 °C

SMILES string

N[C@H]1CCCc2ccccc12

InChI

1S/C10H13N/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-2,4,6,10H,3,5,7,11H2/t10-/m0/s1

InChI key

JRZGPXSSNPTNMA-JTQLQIEISA-N

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Application

(S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine is a chiral amine that can be used:
  • To prepare a 2-pyridylmethylene-(S)-(+)-1,2,3,4-tetrahydro-1-naphthylamine containing pentanuclear trigonal bipyramidal [Co3Fe2] complex, which exhibits electron-transfer-coupled spin transition (ETCST) properties.
  • To prepare imine-substituted thiophene Schiff base compounds.
  • To derivatize macrocyclic diarylheptanoid compounds of biological importance.

Legal Information

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H314,H412

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Skin Corr. 1C

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex
Wei R-J, et al.
Dalton Transactions, 45(43), 17104-17107 (2016)
Synthesis and antibacterial evaluation of macrocyclic diarylheptanoid derivatives
Lin H, et al.
Bioorganic & medicinal chemistry letters, 26(16), 4070-4076 (2016)
Crystal structures of four chiral imine-substituted thiophene derivatives
Hern'andez-T'ellez G, et al.
Acta Crystallographica Section E: Crystallographic Communications, 72(3), 350-354 (2016)

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