Yes, each quantity of this product is packaged using SureSeal closures.
175552
Trichlorosilane
99%
Synonym(s):
Hydrotrichlorosilane, Silicochloroform, Silicon chloride hydride, Trichloromonosilane
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About This Item
Linear Formula:
SiHCl3
CAS Number:
Molecular Weight:
135.45
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
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vapor density
1 (vs air)
Quality Level
vapor pressure
9.75 psi ( 20 °C)
Assay
99%
form
liquid
expl. lim.
70 %
bp
32-34 °C (lit.)
density
1.342 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
Cl[SiH](Cl)Cl
InChI
1S/Cl3HSi/c1-4(2)3/h4H
InChI key
ZDHXKXAHOVTTAH-UHFFFAOYSA-N
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General description
Trichlorosilane is used as a reducing agent in certain chemical reactions or as a starting material for the synthesis of various organosilicon compounds. Trichlorosilane is generally used for the asymmetric hydrosilylation of olefins in the presence of palladium catalysts coordinated with chiral monodentate phosphorus ligands to generate chiral organosilanes.[1]
Application
Trichlorosilane has been used to synthesize 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS) via reduction of 11-dicyclohexylphosphinoyl-12-phenyl-9,10-dihydro-9,10-ethenoanthracene.[2]
Other possible applications:
L-valine-derived catalyst to form secondary amines.[3]
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.[5][6]
Other possible applications:
- Asymmetric reduction of N-aryl ketimines in the presence of a novel
L-valine-derived catalyst to form secondary amines.[3]
- Hydrosilylation of imidazolinones to form chiral imidazolidinones in the presence of a 2,2′-bispyrrolidine based Lewis base organocatalyst.[4]
- Trichlorosilane activated with chiral N-formylproline
derivatives is an effective reagent for the reduction of imines to form
enantiomerically enriched amines.[5][6]
- Trichlorosilane reacts with dimethylformamide to form hypervalent hydridosilicates, which can reduce aldehydes to alcohols, imines to amines, and also for the reductive amination of aldehydes. [7]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1A - Water-react 1
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
<-2.2 °F - Equilibrium method
Flash Point(C)
< -19 °C - Equilibrium method
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Christophe Blaszykowski et al.
Langmuir : the ACS journal of surfaces and colloids, 28(5), 2318-2322 (2012-01-25)
We report herein three unprecedented alkyltrichlorosilane surface modifiers bearing pentafluorophenyl ester (PFP), benzothiosulfonate (BTS), or novel β-propiolactone (BPL) functionalizable terminal groups. Evidence is provided that these molecules can be prepared in very high purity (as assessed by NMR) through a
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As an analogue to the vapor-liquid-solid process, the solution-liquid-solid (SLS) method offers a mild solution-phase route to colloidal 1D nanostructures with controlled sizes, compositions, and properties. However, direct growth of 1D nanostructure arrays through SLS processes remains in its infancy.
New organic activators for the enantioselective reduction of aromatic imines with trichlorosilane
Onomura O
Tetrahedron Letters, 47(22), 3751-3754 (2006)
First chemo-and stereoselective reduction of imines using trichlorosilane activated with N-formylpyrrolidine derivatives
Iwasaki F
Tetrahedron Letters, 42(13), 2525-2527 (2001)
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Are all quantities of HSiCl3 sold in sure seal bottles?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Do you have any pressure specifications for the SureSeal bottles in C20927043, particularly for product 175552-500G?
1 answer-
The inner packaging has undergone a hydrostatic pressure test. For the amber glass bottle PM1305 with SureSeal crown cap PM3314, a hydrostatic pressure test is conducted at 66 psi to ensure no leakage from the container.
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