10452
Ruthenium(III) chloride trihydrate
technical
Synonym(s):
Ruthenium trichloride trihydrate
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About This Item
Linear Formula:
RuCl3 · 3H2O
CAS Number:
Molecular Weight:
261.47
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
technical
form
solid
reaction suitability
core: ruthenium
reaction type: C-H Activation
reagent type: catalyst
SMILES string
O.O.O.Cl[Ru](Cl)Cl
InChI
1S/3ClH.3H2O.Ru/h3*1H;3*1H2;/q;;;;;;+3/p-3
InChI key
ZTWIEIFKPFJRLV-UHFFFAOYSA-K
Application
Ruthenium(III) chloride trihydrate can be used as a catalyst:
- Precursor for the hydroamidation of terminalalkynes.
- For the hydrolysis of 4-nitrobenzonitrile to 4-nitrobenzamide in the presence of 1,3,5-triaza-7-phosphaadamantane.
- For the oxidation of thioethers to sulfones in the presence of sodium periodate and acetonitrile.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A Practical and Effective Ruthenium Trichloride-Based Protocol for the Regio-and Stereoselective Catalytic Hydroamidation of Terminal Alkynes
Goossen L, et al.
advanced synthesis and catalysis, 350, 2701-2707 (2008)
Whalmany L Ounkham et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(42), 10013-10020 (2019-05-18)
RuCl2 (PTA)4 (PTA=1,3,5-triaza-7-phosphaadamantane) is an active, recyclable, air-stable, aqueous-phase nitrile hydration catalyst. The development of an in situ generated aqueous-phase nitrile hydration catalyst (RuCl3 ⋅3 H2 O+6 equivalents PTA) is reported. The activity of the in situ catalyst is comparable to RuCl2
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Chemical Communications (Cambridge, England), 1255-1255 (1986)
Tenaglia, A.; Terranova, E. et al.
Tetrahedron Letters, 32, 1169-1169 (1991)
Sasaki, Y.; Dixneuf, P. H.
The Journal of Organic Chemistry, 52, 314-314 (1987)
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