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249939

Sigma-Aldrich

Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer

96%

Synonym(s):

[Rh(nbd)Cl]2, dichlorobis(norbornadiene)dirhodium, 2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer, [Rh(nbd)Cl]2

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About This Item

Empirical Formula (Hill Notation):
C14H16Cl2Rh2
CAS Number:
12257-42-0
Molecular Weight:
460.99
EC Number:
235-510-4
MDL number:
MFCD00198060
UNSPSC Code:
12161600
PubChem Substance ID:
24855024
NACRES:
NA.22

Quality Level

100

Assay

96%

form

powder

reaction suitability

core: rhodium
reagent type: catalyst

SMILES string

Cl[Rh].Cl[Rh].[CH]1[CH]C2[CH][CH]C1C2.[CH]3[CH]C4[CH][CH]C3C4

InChI

1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+;;;;

InChI key

RXDWVIOULPVOEO-SEGRDSFWSA-L

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Articles

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Hydrosilylation Catalyst

Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

Hydrosilylation Catalyst

Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

Hydrosilylation Catalyst

Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

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