Skip to Content
Merck
All Photos(2)

Documents

160954

Sigma-Aldrich

Methyl 4-nitrobenzenesulfonate

99%

Synonym(s):

Methyl nosylate, Methyl p-nitrobenzenesulfonate, Methyl p-nitrotosylate

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
O2NC6H4SO3CH3
CAS Number:
6214-20-6
Molecular Weight:
217.20
Beilstein:
2277327
EC Number:
228-282-2
MDL number:
MFCD00007344
UNSPSC Code:
12352100
PubChem Substance ID:
24849896
NACRES:
NA.22

Assay

99%

form

solid

mp

89-92 °C (lit.)

solubility

acetone: soluble 5%, clear, faintly yellow to greenish-yellow

SMILES string

COS(=O)(=O)c1ccc(cc1)[N+]([O-])=O

InChI

1S/C7H7NO5S/c1-13-14(11,12)7-4-2-6(3-5-7)8(9)10/h2-5H,1H3

InChI key

RMNJNEUWTBBZPT-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Reaction between methyl 4-nitrobenzenesulfonate and bromide ions has been studied in mixed single-chain-gemini micellar solutions. Kinetics of SN2 reactions of methyl 4-nitrobenzenesulfonate with ammonia, primary amines, secondary amines, tertiary amines and anionic nucleophiles has been studied.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315

Hazard Classifications

Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

L S Chang et al.
Journal of protein chemistry, 15(3), 255-260 (1996-04-01)
The binding of the apolar fluorescent dye 8-anilinonaphthalene-1-sulfonate (ANS) to Naja naja atra phospholipase A2 (PLA2) as well as the enhancement of ANS fluorescence of the PLA2-ANS complex decreased with increasing pH in a pH range from 3 to 9.
M A Porter et al.
The Journal of biological chemistry, 263(29), 14846-14849 (1988-10-15)
The activity of the Calvin cycle enzyme phosphoribulokinase is coupled to photosynthetic electron transport by reversible oxidation/reduction mediated by thioredoxin-f. Previous studies have shown that one of the regulatory sulfhydryl groups, that of Cys-16, is positioned at the nucleotide-binding domain
R P Swenson et al.
The Journal of biological chemistry, 259(9), 5585-5590 (1984-05-10)
Incubation of D-amino acid oxidase with excess methyl-p-nitrobenzenesulfonate results in a pseudo-first order, irreversible loss of 95% of the assayable activity using D-phenylglycine as substrate. The rate of inactivation reaches a limiting value of 0.021 min-1 (pH 7.7, 22 degrees
Cysteine modification of metallothionein.
P E Hunziker
Methods in enzymology, 205, 399-400 (1991-01-01)
J P Marcus et al.
Archives of biochemistry and biophysics, 316(1), 413-420 (1995-01-10)
Incubation of L-threonine dehydrogenase from Escherichia coli with methyl p-nitrobenzenesulfonate results in a time- and concentration-dependent loss of enzymatic activity. As the concentration of the methylating agent is increased, the rate of inactivation reaches a limiting value of 0.01 min-1
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service