CRM68471

Flucythrinate

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): α-Cyano-3-phenoxybenzyl 4-difluoromethoxy-α-isopropylphenylacetate
• Empirical Formula (Hill Notation): C₂₆H₂₃F₂NO₄
• CAS Number: 70124-77-5
• Molecular Weight: 451.46
• MDL number: MFCD00137383
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• storage temp.: 2-8°C
• SMILES string: CC(C)C(C(=O)OC(C#N)c1cccc(Oc2ccccc2)c1)c3ccc(OC(F)F)cc3
• InChI: 1S/C26H23F2NO4/c1-17(2)24(18-11-13-21(14-12-18)32-26(27)28)25(30)33-23(16-29)19-7-6-10-22(15-19)31-20-8-4-3-5-9-20/h3-15,17,23-24,26H,1-2H3
• InChI key: GBIHOLCMZGAKNG-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Flucythrinate is a synthetic a-cyano pyrethroid insecticide that acts as a voltage gated sodium channel agonist. It finds its use to provide protection against a variety of sucking insects, beetles, and lepidoptera in cotton and pome fruits.
Flucythrinate is not approved for its use in the European Union (EU) as per the Commission Regulation (EC) No 2076/2002 of 20th November 2002 as a plant protection agent under the Regulation (EC) No. 1107/2009, repealing the directive 91/414/EEC. Flucythrinate is measured and reported along with other mixtures of its constituent isomers (sum of isomers). But a default maximum residue limit (MRL) of 0.01 mg/kg and 0.02 mg/kg is applicable for its presence in fresh/frozen fruits and tree nuts respectively according to Reg. (EU) 2015/868.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The methiocarb CRM may also find use as given below:

• Development of a class selective enzyme-linked immunosorbent assay (ELISA) to screen a-cyano pyrethroids and their metabolites
• Comparison between two sample preparation techniques-dispersive liquid-liquid microextraction (DLLME) and QuEChERS-DLLME, followed by gas chromatography-electron capture detection (GC-ECD) for the determination of 10 pyrethroids from different fruit juice samples
• Multi-residue analysis of 133 pesticide residues in chenpi samples using a modified QuEChERS method and gas chromatography-tandem mass spectrometry (GC-MS/MS)
• Simultaneous determination of 78 pesticides in black tea samples using multi-walled carbon nanotubes (MWCNTs) for dispersive solid phase extraction (d-SPE) accompanied by quantification with gas chromatography-tandem mass spectrometry (GC-MS/MS)
• Development of a method based on gas chromatography-mass spectrometry (GC-MS) in negative chemical ionization mode to determine 17 pyrethroid residues in garlic, onion, spring onion, and chili samples
• Development and validation of a method for multi-residue analysis of 124 pesticides in rice samples using modified QuEChERS extraction and gas chromatography-tandem mass spectrometry (GC-MS/MS)

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS02,GHS06,GHS09
• Signal Word: Danger
• Hazard Statements: H226,H301,H332,H410
• Precautionary Statements: P210 - P233 - P240 - P273 - P301 + P310 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 113.0 °F
• Flash Point(C): 45 °C