128422
mono-Ethyl fumarate
95%
Synonym(s):
Fumaric acid monoethyl ester, Monoethyl fumarate
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About This Item
Linear Formula:
C2H5OCOCH=CHCOOH
CAS Number:
Molecular Weight:
144.13
Beilstein:
1723588
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
95%
form
solid
bp
147 °C/16 mmHg (lit.)
mp
66-68 °C (lit.)
SMILES string
CCOC(=O)\C=C\C(O)=O
InChI
1S/C6H8O4/c1-2-10-6(9)4-3-5(7)8/h3-4H,2H2,1H3,(H,7,8)/b4-3+
InChI key
XLYMOEINVGRTEX-ONEGZZNKSA-N
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Related Categories
Application
mono-Ethyl fumarate (fumaric acid monoethyl ester, monoethyl fumarate) was used in the preparation of photo-crosslinkable macromers. It was also used to synthesize Ugi/intramolecular Diels-Alder (IMDA) cycloaddition products.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Janine Jansen et al.
Biomacromolecules, 10(2), 214-220 (2008-12-19)
Polymer networks were prepared by photocross-linking fumaric acid monoethyl ester (FAME) functionalized, three-armed poly(D,L-lactide) oligomers using N-vinyl-2-pyrrolidone (NVP) as diluent and comonomer. The use of NVP together with FAME-functionalized oligomers resulted in copolymerization at high rates, and networks with gel
Treatment of recurrent aphthous stomatitis with fumaric acid esters.
Emmanuella Guenova et al.
Archives of dermatology, 147(3), 282-284 (2011-03-23)
J Z Hu et al.
Solid state nuclear magnetic resonance, 6(1), 85-94 (1996-02-01)
The 1H magic-angle spinning (MAS) spectrum for a typical powdered solid is composed of a high resolution component and a broadline component. The high resolution component can be well isolated from the broadline component by the Hahn echo sequence with
Janine Jansen et al.
Acta biomaterialia, 8(10), 3652-3659 (2012-06-19)
Photo-crosslinked networks were prepared from fumaric acid monoethyl ester-functionalized poly(D,L-lactic acid) oligomers and N-vinyl-2-pyrrolidone. Two model proteins, lysozyme and albumin, were incorporated into the network films as solid particles and their release behavior was studied. By varying the NVP content
K Paulvannan
The Journal of organic chemistry, 69(4), 1207-1214 (2004-02-14)
An efficient approach to rigid tricyclic nitrogen heterocycles via sequential and tandem Ugi/intramolecular Diels-Alder (IMDA) cycloaddition of pyrrole is described. The one-pot Ugi four-component condensation (4CC) reaction was used as the key transformation to prepare trienes with a carboxamide substituent
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