307963
2,6-Dimethyl-5-heptenal
technical grade, 80%
Synonym(s):
Melonal
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About This Item
Linear Formula:
(CH3)2C=CHCH2CH2CH(CH3)CHO
CAS Number:
Molecular Weight:
140.22
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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grade
technical grade
Quality Level
Assay
80%
form
liquid
refractive index
n20/D 1.444 (lit.)
bp
116-124 °C/100 mmHg (lit.)
density
0.879 g/mL at 25 °C
functional group
aldehyde
SMILES string
CC(CC\C=C(\C)C)C=O
InChI
1S/C9H16O/c1-8(2)5-4-6-9(3)7-10/h5,7,9H,4,6H2,1-3H3
InChI key
YGFGZTXGYTUXBA-UHFFFAOYSA-N
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General description
2,6-Dimethyl-5-heptenal (melonal) and 5-heptenal undergo concerted ene reaction to form zwitterion that further reacts to give ene product[1].
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Sens. 1B
Storage Class Code
10 - Combustible liquids
WGK
WGK 2
Flash Point(F)
143.6 °F
Flash Point(C)
62 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Alkylaluminum halide induced cyclization of unsaturated carbonyl compounds.
Snider BB, et al.
The Journal of Organic Chemistry, 47(23), 4538-4545 (1982)
I F Gaunt et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 21(5), 543-549 (1983-10-01)
Groups of 15 male and 15 female rats were fed for at least 90 days on diets that provided 2,6-dimethylhept-5-en-1-al (DMH) at average intakes of 0 (control), 9, 37 and 150 mg/kg body weight/day. Steps were taken to limit loss
Natali Amar-Zrihen et al.
Journal of agricultural and food chemistry, 59(10), 5554-5564 (2011-04-19)
Four lipophilic food volatile molecules of different chemical characteristics, phenylacetaldehyde, 2,6-dimethyl-5-heptenal, linalool, and trans-4-decenal, were solubilized into binary mixtures of monoolein/water, facilitating the formation of reverse hexagonal (H(II)) mesophases at room temperature without the need of solvents or triglycerides. Some
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