CRM05394
Fenazaquin
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
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About This Item
Empirical Formula (Hill Notation):
C20H22N2O
CAS Number:
Molecular Weight:
306.40
Beilstein:
8331263
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24
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grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
form
solid
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
storage temp.
2-8°C
SMILES string
CC(C)(C)c1ccc(CCOc2ncnc3ccccc23)cc1
InChI
1S/C20H22N2O/c1-20(2,3)16-10-8-15(9-11-16)12-13-23-19-17-6-4-5-7-18(17)21-14-22-19/h4-11,14H,12-13H2,1-3H3
InChI key
DMYHGDXADUDKCQ-UHFFFAOYSA-N
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Fenazaquin is an insecticide/acaricide that belongs to the class of quinazoline compounds. It shows ovicidal activity against phytophagus mites found in agricultural crops of almonds, citrus fruits, and grapes. It is highly lipophilic and inhibits site I of the electron transport chain in mitochondria. Its acceptable daily intake (ADI) according to body weight is 0.005 mg/kg.
Fenazaquin was approved for use in the European Union on 1st June 2011 following a request for its inclusion according to Reg. 33/2008 and its approval for use expires on 31st May 2023. The maximum residue limit (MRL) for fenazaquin in citrus fruits is 0.5 mg/kg and 0.2 mg/kg in tree nuts. Fenazaquin is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Fenazaquin is an insecticide/acaricide that belongs to the class of quinazoline compounds. It shows ovicidal activity against phytophagus mites found in agricultural crops of almonds, citrus fruits, and grapes. It is highly lipophilic and inhibits site I of the electron transport chain in mitochondria. Its acceptable daily intake (ADI) according to body weight is 0.005 mg/kg.
Fenazaquin was approved for use in the European Union on 1st June 2011 following a request for its inclusion according to Reg. 33/2008 and its approval for use expires on 31st May 2023. The maximum residue limit (MRL) for fenazaquin in citrus fruits is 0.5 mg/kg and 0.2 mg/kg in tree nuts. Fenazaquin is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
It may also find following uses:
It may also find following uses:
- Determination of trace levels of fenazaquin in raw almond samples using dispersive magnetic solid phase extraction (DMSPE) and gas chromatography-mass spectrometry (GC-MS)
- Development of a liquid phase microextraction method using eutectic solvents for extraction from different fruit and vegetable samples and gas chromatography determination
- Switchable solvent microextraction of pesticide residues from food and environmental samples
- Evaluation of 60 pesticide residues in 144 different fruit and vegetable samples by LC-MS/MS method
- Study of matrix effects in pesticide residue analysis in different citrus fruits using ethyl acetate for extraction and Ultrahigh-Performance Liquid Chromatography–High-Resolution Mass Spectrometry for determination
- Residue analysis of 64 pesticides from various groups by nanoflow liquid chromatography-mass spectrometry (LC-MS)
Recommended products
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Natalia Besil et al.
Journal of agricultural and food chemistry, 65(23), 4819-4829 (2017-05-26)
The matrix effects of ethyl acetate extracts from seven different citrus fruits on the determination of 80 pesticide residues using liquid chromatography coupled to high-resolution time-of-flight mass spectrometry (UHPLC-(ESI)-HR-TOF) at 4 GHz resolution mode were studied. Only 20% of the
Anna Stachniuk et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 52(7), 446-457 (2017-03-30)
The aim of the research is to evaluate pesticide residue contamination of fresh and frozen fruits and vegetables, agricultural raw material, purchased from Polish farmers for production of frozen fruits and vegetables, and the estimation of the multiresidue method effectiveness
Application of oleic acid functionalized magnetic nanoparticles for a highly sensitive and efficient dispersive magnetic solid phase extraction of fenazaquin in almond samples for determination by gas chromatrography mass spectrometry
Turan N B, et al.
Microchemical Journal, Devoted to the Application of Microtechniques in All Branches of Science, 104329 (2020)
Development of a new temperature-controlled liquid phase microextraction using deep eutectic solvent for extraction and preconcentration of diazinon, metalaxyl, bromopropylate, oxadiazon, and fenazaquin pesticides from fruit juice and vegetable samples followed by gas chromatography-flame ionization detection
Farajzadeh M A, et al.
Journal of food composition and analysis, 66, 90-97 (2018)
David Moreno-González et al.
Journal of chromatography. A, 1512, 78-87 (2017-07-20)
This article reports on the evaluation of nanoflow liquid chromatography-mass spectrometry (LC-MS) for pesticide residue analysis in food. The approach is based on the use of reversed-phase C18nano columns with an integrated emitter, so that separation, ionization and detection are
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