The Journal of chemical physics, 137(22), 22A551-22A551 (2012-12-20)
The standard model for molecular recognition of an odorant is that receptor sites discriminate by molecular geometry as evidenced that two chiral molecules may smell very differently. However, recent studies of isotopically labeled olfactants indicate that there may be a
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 91, 329-337 (2012-03-14)
Four tetradentate (N(2)O(2)) and tridentate (NO(2)) Schiff base compounds (L1-L4) with propargyl moiety were prepared by the condensation of 1-[2-hydroxy-4-(prop-2-yn-1-yloxy)phenyl]ethanone with various aliphatic amines. The newly synthesized compounds (L1-L4) were characterized on the basis of the results of elemental analysis
Insect biochemistry and molecular biology, 43(2), 209-218 (2013-01-01)
Arterenone (2-amino-3',4'-dihydroxy acetophenone) is an important hydrolytic product generated from lightly colored sclerotized cuticle that use N-acyldopamine derivatives for crosslinking reactions. It seems to arise from 1,2-dehydro-N-acetyldopamine (dehydro NADA) that has been crosslinked to the cuticular components. However, the mechanism
The hydrogenation of ketones catalyzed by 2,6-bis(diisopropylphosphinomethyl)pyridine (PNP)-ligated iron pincer complexes was studied using the range-separated and dispersion-corrected ωB97X-D functional in conjunction with the all-electron 6-31++G(d,p) basis set. A validated structural model in which the experimental isopropyl groups were replaced
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