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17631

Sigma-Aldrich

3-Bromomethyl-7-methoxy-1,4-benzoxazin-2-one

BioReagent, suitable for fluorescence, ≥97.0%

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About This Item

Empirical Formula (Hill Notation):
C10H8BrNO3
CAS Number:
Molecular Weight:
270.08
MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:

product line

BioReagent

Assay

≥97.0%

mp

144-148 °C

fluorescence

λex 343 nm; λem 430 nm

suitability

suitable for fluorescence

storage temp.

2-8°C

SMILES string

COc1ccc2N=C(CBr)C(=O)Oc2c1

InChI

1S/C10H8BrNO3/c1-14-6-2-3-7-9(4-6)15-10(13)8(5-11)12-7/h2-4H,5H2,1H3

InChI key

XFCZURAACWKKIH-UHFFFAOYSA-N

Other Notes

Highly sensitive fluorescent derivatizing agent for carboxylic acids; detection at 440 nm with excitation at 345 nm

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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A. Nakanishi et al.
Journal of Chromatography A, 591, 159-159 (1992)
J Yamada et al.
Analytical biochemistry, 199(1), 132-136 (1991-11-15)
A sensitive nonradioisotopic method is reported for measuring microsomal lauric acid omega-hydroxylation activity. The assay is based upon separation and detection of 12-hydroxylauric acid formed by means of high-performance liquid chromatography following fluorescence labeling of the carboxyl group with 3-bromomethyl-7-methoxy-1,4-benzoxazin-2-one
Kwan Soo Kim et al.
Journal of the American Chemical Society, 130(26), 8537-8547 (2008-06-06)
An efficient direct one-pot glycosylation method with anomeric hydroxy sugars as glycosyl donors employing phthalic anhydride and triflic anhydride as activating agents has been developed. Thus, highly stereoselective beta-mannopyranosylations were achieved by the reaction of 2,3-di-O-benzyl-4,6-O-benzylidene-D-mannopyranose (2) with phthalic anhydride

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